Safety Data Sheet - Potassium Permanganate

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Potassium Permanganate

Product Form Substance

Catalogue No. AL3753

CAS Number 7722-64-7

EC Number 231-760-3

EC Index Number Permanganate, potassium

Grade AR

HSN Code 28416100

Molecular Formula KMnO4

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Potassium Permanganate

Catalogue No. AL3753

Product form Substance

CAS Number 7722-64-7

EC Number 231-760-3

Grade AR

EC Index Number Permanganate, potassium

Chemical Formula KMnO4

HSN Code 28416100

Synonyms Permanganate of Potash, KMnO4

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Analytical reagent, oxidizing agent

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Ox. Sol. 2; Acute Tox. 4; Aquatic Acute 1; Aquatic Chronic 1

Classification source ECHA C&L Inventory via PubChem CID 516875 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Oxidizer, Irritant, Environmental Hazard

Signal word Danger

Hazard statements H272: May intensify fire; oxidizer; H302: Harmful if swallowed; H400: Very toxic to aquatic life; H410: Very toxic to aquatic life with long lasting effects

2.3 Other hazards

Other hazards Strong oxidizer; may cause fire or explosion in contact with combustible materials.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Potassium Permanganate

CAS No. 7722-64-7

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact Wash with plenty of soap and water. Seek medical attention if irritation develops.

First-aid measures after eye contact Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.

First-aid measures after ingestion Induce vomiting and follow with thorough gastric lavage, demulcents, glucose I.V., fluid therapy, and antibiotics. Tracheostomy may be lifesaving.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Irritation of the respiratory tract, skin burns, and eye damage.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures The material itself is noncombustible but it will accelerate the burning of combustible material. If the combustible material is finely divided the mixture may be explosive.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Contain spill and prevent entry into waterways. Use appropriate protective equipment.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. Carefully collect remainder.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Handle with gloves and eye protection. Avoid contact with skin and eyes.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from combustible substances, reducing agents and powdered metals. Well closed. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if dust is generated.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Solid

Colour Dark purple to black

Odour Characteristic

Odour threshold No data available

pH value No data available

Relative evaporation rate (butylacetate=1) No data available

Melting point 240 °C (464 °F)

Freezing point No data available

Boiling point Decomposes before boiling

Flash point No data available

Auto-ignition temperature No data available

Decomposition temperature > 240 °C

Flammability (solid, gas) Not flammable, but a strong oxidizer

Vapour pressure No data available

Relative vapour density at 20°C No data available

Density 2.703 g/cm³

Solubility 6.4 g/100 mL in water at 20 °C

Log Pow No data available

Viscosity, kinematic No data available

Viscosity, dynamic No data available

Explosive properties Not explosive

Oxidising properties Strong oxidizer

Explosive limits No data available

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Reacts violently with reducing agents and combustible materials.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on heating. This produces toxic gases and irritating fumes. The substance is a strong oxidant.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Reducing agents, organic materials, and acids.

10.6 Hazardous decomposition products

Hazardous decomposition products Not specified

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Guinea pig oral 810 mg/kg.; LD50 Mouse oral 750 mg/kg

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1490

UN-No. (IMDG) UN 1490

UN-No. (IATA) UN 1490

UN-No. (ADN) UN 1490

UN-No. (RID) UN 1490

14.2 UN proper shipping name

Proper Shipping Name (ADR) Potassium Permanganate

Proper Shipping Name (IMDG) Potassium Permanganate

Proper Shipping Name (IATA) Potassium Permanganate

Proper Shipping Name (ADN) Potassium Permanganate

Proper Shipping Name (RID) Potassium Permanganate

14.3 Transport hazard class(es)

Transport hazard class(es) 5.1

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.