Propargyl Alcohol
Synonyms: 2-Propyn-1-ol
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Propargyl Alcohol
Product Form
Substance
Catalogue No.
AL3812
CAS Number
107-19-7
EC Number
203-471-2
EC Index Number
603-058-00-2
Grade
99%
HSN Code
29052900
Molecular Formula
C3H4O
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Propargyl Alcohol
Catalogue No.
AL3812
Product form
Substance
CAS Number
107-19-7
EC Number
203-471-2
Grade
99%
EC Index Number
603-058-00-2
Chemical Formula
C3H4O
HSN Code
29052900
Synonyms
2-Propyn-1-ol
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Synthetic intermediate, corrosion inhibitor
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 3; Acute Tox. 3; Acute Tox. 2; Skin Corr. 1B; Eye Dam. 1; Aquatic Chronic 2
Classification source
ECHA C&L Inventory via PubChem CID 7859 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Flammable, Corrosive, Acute Toxic, Environmental Hazard
Signal word
Danger
Hazard statements
H226: Flammable liquid and vapor; H301: Toxic if swallowed; H310: Fatal in contact with skin; H314: Causes severe skin burns and eye damage; H318: Causes serious eye damage; H331: Toxic if inhaled; H411: Toxic to aquatic life with long lasting effects
2.3 Other hazards
Other hazards
Highly toxic and flammable; may cause respiratory irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Propargyl Alcohol
CAS No.
107-19-7
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, flush the contaminated skin with water promptly. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water promptly. If irritation persists after washing, get medical attention.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Symptoms of exposure may include headache, dizziness, nausea, and respiratory distress.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Ventilate the area. Use appropriate protective equipment. Prevent entry into waterways, sewers, or confined areas.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use only in a fume hood. Wear appropriate personal protective equipment (PPE) including gloves and goggles. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Fireproof. Separated from strong oxidants and food and feedstuffs. Keep in the dark. Well closed.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a NIOSH-approved respirator if exposure limits are exceeded or if irritation occurs.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Mild, geranium odor
Odour threshold
Not specified
pH value
Not specified
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-48 to -52 °C
Freezing point
Not specified
Boiling point
114-115 °C at 760 mm Hg; 100 °C at 490.3 mm Hg; 70 °C at 147.6 mm Hg; 20 °C at
Flash point
97 °F (36 °C) (Open cup)
Auto-ignition temperature
Not specified
Decomposition temperature
Not specified
Flammability (solid, gas)
Flammable liquid
Vapour pressure
15.6 mm Hg at 25 °C
Relative vapour density at 20°C
Relative vapor density (air = 1): 1.93
Density
0.9715 at 20 °C/4 °C
Solubility
Miscible with water and organic solvents
Log Pow
-0.38
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not specified
Oxidising properties
Not specified
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts with strong oxidizing agents and bases.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
The substance may polymerize under the influence of heat, oxidizers, peroxides and light. Reacts violently with oxidants. Attacks many plastics.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong acids, and bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
Not specified
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral, male: 110 (100-120) mgkg, female: 55 (50-60) mgkg; LD50 Guinea pig oral 60 mg/kg; LC50 Rat (female) inhalation 1040 ppm/1 hr
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
2929
UN-No. (IMDG)
2929
UN-No. (IATA)
2929
UN-No. (ADN)
2929
UN-No. (RID)
2929
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Propargyl Alcohol
Proper Shipping Name (IMDG)
Propargyl Alcohol
Proper Shipping Name (IATA)
Propargyl Alcohol
Proper Shipping Name (ADN)
Propargyl Alcohol
Proper Shipping Name (RID)
Propargyl Alcohol
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1 (3)
14.4 Packing group
Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.