Propionic Anhydride
Synonyms: Propanoic anhydride
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Propionic Anhydride
Product Form
Substance
Catalogue No.
AL3815
CAS Number
123-62-6
EC Number
204-638-2
EC Index Number
607-007-00-8
Grade
98%
HSN Code
29155000
Molecular Formula
C6H10O3
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Propionic Anhydride
Catalogue No.
AL3815
Product form
Substance
CAS Number
123-62-6
EC Number
204-638-2
Grade
98%
EC Index Number
607-007-00-8
Chemical Formula
C6H10O3
HSN Code
29155000
Synonyms
Propanoic anhydride
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Acylating reagent in organic synthesis
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Skin Corr. 1B
Classification source
ECHA C&L Inventory via PubChem CID 31263 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Corrosive
Signal word
Danger
Hazard statements
H314: Causes severe skin burns and eye damage
2.3 Other hazards
Other hazards
Corrosive to metals
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Propionic Anhydride
CAS No.
123-62-6
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move victim to fresh air; if breathing has stopped, give artificial respiration.
First-aid measures after skin contact
Immediately flush with plenty of water for at least 15 min.
First-aid measures after eye contact
Immediately flush with plenty of water for at least 15 min.; get medical attention.
First-aid measures after ingestion
Give large amount of water, do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of the skin, eyes, and respiratory tract; potential burns on contact.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
The vapour is heavier than air.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Contain spill and absorb with inert material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: chemical protection suit including self-contained breathing apparatus, face shield and protective gloves. Collect leaking liquid in sealable containers. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use in a fume hood with appropriate personal protective equipment (PPE).
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Dry. Ventilation along the floor. Separated from bases, oxidants and food and feedstuffs. Store only in original container.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Very rancid odor
Odour threshold
No data available
pH value
No data available
Relative evaporation rate (butylacetate=1)
No data available
Melting point
-45 °C
Freezing point
No data available
Boiling point
170 °C
Flash point
165 °F (74 °C) (Open Cup)
Auto-ignition temperature
285 °C (545 °F)
Decomposition temperature
No data available
Flammability (solid, gas)
Flammable liquid
Vapour pressure
VP: 1 mm Hg at 20.6 °C
Relative vapour density at 20°C
4.49 (Air = 1)
Density
1.011 g/cu cm at 20 °C
Solubility
Decomposed by water; soluble in methanol, ethanol, ether and chloroform
Log Pow
No data available
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
No data available
Oxidising properties
No data available
Explosive limits
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts violently with water, releasing heat and forming propionic acid.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on contact with water. This produces corrosive propionic acid (see ICSC 0806). Reacts violently with bases and oxidants.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Water, strong oxidizing agents, strong bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits acrid smoke and irritating fumes.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 2360 mg/kg; LD50 Rabbit skin 10,000 mg/kg
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 2496
UN-No. (IMDG)
UN 2496
UN-No. (IATA)
UN 2496
UN-No. (ADN)
UN 2496
UN-No. (RID)
UN 2496
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Propionic anhydride
Proper Shipping Name (IMDG)
Propionic anhydride
Proper Shipping Name (IATA)
Propionic anhydride
Proper Shipping Name (ADN)
Propionic anhydride
Proper Shipping Name (RID)
Propionic anhydride
14.3 Transport hazard class(es)
Transport hazard class(es)
8
14.4 Packing group
Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.