Sodium Bisulfite
Synonyms: Sodium acid sulfite
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Sodium Bisulfite
Product Form
Substance
Catalogue No.
AL4087
CAS Number
7631-90-5
EC Number
231-548-0
EC Index Number
016-063-00-2
Grade
Standard grade
HSN Code
28321010
Molecular Formula
NaHSO3
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Sodium Bisulfite
Catalogue No.
AL4087
Product form
Substance
CAS Number
7631-90-5
EC Number
231-548-0
Grade
Standard grade
EC Index Number
016-063-00-2
Chemical Formula
NaHSO3
HSN Code
28321010
Synonyms
Sodium acid sulfite
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Reducing agent, food preservative, reference compound
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4
Classification source
ECHA C&L Inventory via PubChem CID 23665763 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Irritant
Signal word
Warning
Hazard statements
H302: Harmful if swallowed
Precautionary statements
P264, P270, P301+P317, P330, P501
2.3 Other hazards
Other hazards
Releases irritating sulfur dioxide gas upon decomposition.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Sodium Bisulfite
CAS No.
7631-90-5
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
If a person breathes large amounts of this chemical, move the exposed person to fresh air at once.
First-aid measures after skin contact
Wash with plenty of water.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of the respiratory tract, skin, and eyes; potential allergic reactions.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
May emit sulfur dioxide gas when heated or involved in a fire.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Avoid breathing dust. Use appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: filter respirator for acid gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in covered non-metallic containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Wash away remainder with plenty of water.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Avoid contact with skin and eyes. Use in a well-ventilated area. Wear appropriate personal protective equipment.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Separated from acids, strong oxidants and food and feedstuffs. Well closed.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust or mist is generated.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
White to pale yellow
Odour
Slight sulfurous odor
Odour threshold
Not specified
pH value
4.5 (1% solution)
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
less than 32 °F
Freezing point
Not specified
Boiling point
104 °C
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not specified
Flammability (solid, gas)
Not flammable under normal conditions
Vapour pressure
Vapor pressure, kPa at 20 °C: 2.4
Relative vapour density at 20°C
Not specified
Density
1.48
Solubility
Sol in 3.5 parts cold water, in 2 parts boiling water, in about 70 parts alcohol.
Log Pow
Not specified
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions; may react with strong acids and oxidizing agents.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on heating and on contact with acids. This produces sulfur oxides. Reacts with acids and strong oxidants.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong acids, strong oxidizers, and moisture.
10.6 Hazardous decomposition products
Hazardous decomposition products
Emits toxic fumes of oxides of sulfur & sodium monoxide when heated to decomposition.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 2 g/kg; LD50 Rat iv 115 mg/kg; LD50 MOUSE IV 130 MG/KG
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Sodium bisulfite
Proper Shipping Name (IMDG)
Sodium bisulfite
Proper Shipping Name (IATA)
Sodium bisulfite
Proper Shipping Name (ADN)
Sodium bisulfite
Proper Shipping Name (RID)
Sodium bisulfite
14.3 Transport hazard class(es)
Transport hazard class(es)
Not classified as hazardous for transport
14.4 Packing group
Packing group (ADR)
Not applicable
Packing group (IMDG)
Not applicable
Packing group (IATA)
Not applicable
Packing group (ADN)
Not applicable
Packing group (RID)
Not applicable
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.