Sulfur
Synonyms: Sulfur flower, Elemental sulfur
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Sulfur
Product Form
Substance
Catalogue No.
AL4406
CAS Number
7704-34-9
EC Number
231-722-6
EC Index Number
7704-34-9
Grade
98% Extra Pure
HSN Code
25030010
Molecular Formula
S
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Sulfur
Catalogue No.
AL4406
Product form
Substance
CAS Number
7704-34-9
EC Number
231-722-6
Grade
98% Extra Pure
EC Index Number
7704-34-9
Chemical Formula
S
HSN Code
25030010
Synonyms
Sulfur flower, Elemental sulfur
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used in vulcanization, fungicide applications, and general chemistry.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Skin Irrit. 2
Classification source
CLP Annex VI (harmonised EU classification) via PubChem CID 5362487
2.2 Label elements
Hazard pictograms
Irritant
Signal word
Warning
Hazard statements
H315: Causes skin irritation
Precautionary statements
P264, P280, P302+P352, P321, P332+P317, P362+P364
2.3 Other hazards
Other hazards
Flammable solid; may cause fire or explosion if not handled properly.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Sulfur
CAS No.
7704-34-9
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Rinse mouth. Do not induce vomiting. Seek medical attention if symptoms occur.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of the respiratory tract, skin, and eyes.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Burns with a pale blue flame that may be difficult to see in daylight.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and eliminate all ignition sources. Use appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Avoid contact with skin and eyes. Use in a well-ventilated area and keep away from heat sources.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Fireproof. Separated from strong oxidants.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust is generated.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
Pale yellow
Odour
Pure sulfur is odorless, but traces of hydrocarbon impurity may impart an oily and/or rotten egg odor
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
95.3 °C (Sulfur rhombic transforms to monoclinic); 115.21 °C
Freezing point
Not applicable
Boiling point
444.61 °C
Flash point
405 °F (207 °C) (Closed cup)
Auto-ignition temperature
450 °F (232 °C)
Decomposition temperature
Not specified
Flammability (solid, gas)
Flammable solid
Vapour pressure
3.95X10-6 mm Hg at 30.4 °C
Relative vapour density at 20°C
Density of vapor/density of air, 470 °C: 7.837
Density
2.07 gcu cm (Sulfur (rhombic); 2.00 (Sulfur (monoclinic)/
Solubility
Insoluble in water; slightly soluble in ethanol, benzene, ethyl ether; soluble in carbon disulfide
Log Pow
Not specified
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions; may react with strong oxidizing agents.
10.2 Chemical stability
Chemical stability
Preparations containing sulfur may react with metals including silver and copper, resulting in discoloration of the metal.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
On combustion, forms toxic and corrosive gases of sulfur oxides including sulfur dioxide (see ICSC 0074). Reacts violently with strong oxidants , especially if powdered. This generates fire and explosion hazard.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong acids.
10.6 Hazardous decomposition products
Hazardous decomposition products
Not specified
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rabbit dermal >2000 mg/kg bw; LC50 Hamster inhalation >0.047 mg/L 4 hr; LC50 Mouse inhalation >0.047 mg/L 4 hr
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
1350
UN-No. (IMDG)
1350
UN-No. (IATA)
1350
UN-No. (ADN)
1350
UN-No. (RID)
1350
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Sulfur
Proper Shipping Name (IMDG)
Sulfur
Proper Shipping Name (IATA)
Sulfur
Proper Shipping Name (ADN)
Sulfur
Proper Shipping Name (RID)
Sulfur
14.3 Transport hazard class(es)
Transport hazard class(es)
4.1
14.4 Packing group
Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.