Safety Data Sheet - Sulfuryl Chloride

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Sulfuryl Chloride

Product Form Substance

Catalogue No. AL4429

CAS Number 7791-25-5

EC Number 232-245-6

EC Index Number -

Grade 98% For Synthesis

HSN Code 28121090

Molecular Formula SO2Cl2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Sulfuryl Chloride

Catalogue No. AL4429

Product form Substance

CAS Number 7791-25-5

EC Number 232-245-6

Grade 98% For Synthesis

EC Index Number Not specified

Chemical Formula SO2Cl2

HSN Code 28121090

Synonyms Sulfur dichloride oxide

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Chlorinating and sulfonylating reagent in organic synthesis

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Skin Corr. 1C; STOT SE 3

Classification source ECHA C&L Inventory via PubChem CID 24648 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Corrosive, Irritant

Signal word Danger

Hazard statements H314: Causes severe skin burns and eye damage; H335: May cause respiratory irritation

2.3 Other hazards

Other hazards Highly toxic and corrosive; reacts violently with water.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Sulfuryl Chloride

CAS No. 7791-25-5

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Remove to fresh air; administer artificial respiration if required.

First-aid measures after skin contact Wash with large amounts of water.

First-aid measures after eye contact Flush with water for at least 15 min.

First-aid measures after ingestion Give water or milk; do NOT induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Symptoms of exposure may include coughing, difficulty breathing, skin burns, and eye irritation.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Corrosive. Water reactive.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Use appropriate protective equipment. Contain and neutralize spill with sodium bicarbonate or lime.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Handle under a fume hood with appropriate PPE including gloves, goggles, and protective clothing.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from strong bases. Dry.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use a NIOSH-approved respirator when handling this substance in poorly ventilated areas.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless to pale yellow

Odour Very pungent odor

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not specified

Melting point -54.1 °C

Freezing point Not specified

Boiling point 69.3 °C

Flash point Not applicable

Auto-ignition temperature Not applicable

Decomposition temperature Not specified

Flammability (solid, gas) Not flammable

Vapour pressure Vapor pressure = 100 mm Hg at 17.8 °C

Relative vapour density at 20°C 4.6 (Air = 1)

Density 1.6674 at 20 °C/4 °C

Solubility Miscible with benzene, toluene, ether, glacial acetic acid, and other org solvents

Log Pow Not specified

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not applicable

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Highly reactive with water and strong bases; may polymerize under certain conditions.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes under the influence of moist air. This produces chlorine, sulfur oxide, sulfuric acid and hydrogen chloride. Reacts violently with water.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Water, strong bases, and oxidizing agents.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits highly toxic fumes of hydrogen chloride and sulfur oxides.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LC50 Rat, female, inhalation (1 hr) = 242 ppm (1330 mg/cu m); LC50 Rat, male, inhalation (1 hr) = 131 ppm (720 mg/cu m); LD50 Rat, male, Sprague-Dawley, inhalation (4 hr) = 878 mgcu m (159 ppm)/ (sulfuryl chloride vapor, purity 100%)

Skin corrosion/irritation H314: Causes severe skin burns and eye damage

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) H335: May cause respiratory irritation

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1834

UN-No. (IMDG) UN 1834

UN-No. (IATA) UN 1834

UN-No. (ADN) UN 1834

UN-No. (RID) UN 1834

14.2 UN proper shipping name

Proper Shipping Name (ADR) Sulfuryl Chloride

Proper Shipping Name (IMDG) Sulfuryl Chloride

Proper Shipping Name (IATA) Sulfuryl Chloride

Proper Shipping Name (ADN) Sulfuryl Chloride

Proper Shipping Name (RID) Sulfuryl Chloride

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1 (8)

14.4 Packing group

Packing group (ADR) I

Packing group (IMDG) I

Packing group (IATA) I

Packing group (ADN) I

Packing group (RID) I

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.