Safety Data Sheet - 1,1,2,2-Tetrachloroethane

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name 1,1,2,2-Tetrachloroethane

Product Form Substance

Catalogue No. AL4473

CAS Number 79-34-5

EC Number 201-197-8

EC Index Number 602-007-00-0

Grade Extra Pure

HSN Code 29031910

Molecular Formula C2H2Cl4

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name 1,1,2,2-Tetrachloroethane

Catalogue No. AL4473

Product form Substance

CAS Number 79-34-5

EC Number 201-197-8

Grade Extra Pure

EC Index Number 602-007-00-0

Chemical Formula C2H2Cl4

HSN Code 29031910

Synonyms Tetrachloroethane, Perchloroethane

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Used as a reference compound in specialty solvent research and environmental studies.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 1; Acute Tox. 2; Aquatic Chronic 2

Classification source ECHA C&L Inventory via PubChem CID 6591 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Acute Toxic, Environmental Hazard

Signal word Danger

Hazard statements H310: Fatal in contact with skin; H330: Fatal if inhaled; H411: Toxic to aquatic life with long lasting effects

2.3 Other hazards

Other hazards Suspected carcinogen; may cause reproductive toxicity.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name 1,1,2,2-Tetrachloroethane

CAS No. 79-34-5

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention immediately.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Symptoms of exposure may include headache, dizziness, nausea, and respiratory distress.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures May produce toxic fumes in a fire. Use water spray to cool containers exposed to fire.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Wear appropriate protective equipment. Contain and absorb spill with inert material.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Ventilation. Collect leaking liquid in covered containers.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Handle in a fume hood with appropriate personal protective equipment (PPE). Avoid contact with skin and eyes.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from strong bases, alkali metals and food and feedstuffs. Well closed. Cool. Keep in the dark. Ventilation along the floor. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use a NIOSH-approved respirator if exposure limits are exceeded.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless

Odour Sweetish suffocating chloroform-like odor

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not specified

Melting point -42.3 °C

Freezing point Not specified

Boiling point 146.0 °C

Flash point Not specified

Auto-ignition temperature Not specified

Decomposition temperature Not specified

Flammability (solid, gas) Not flammable

Vapour pressure 5.74 mm Hg at 25 °C

Relative vapour density at 20°C 5.79 (Air = 1)

Density 1.5953 g/cu cm at 20 °C

Solubility In water, 2,830 mg/L at 25 °C

Log Pow 2.39

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not specified

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Reacts with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable in abscence of air, moisture and light, even at high temperatures.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on heating and under the influence of air, UV light and moisture. This produces toxic and corrosive gases including hydrogen chloride and phosgene. Reacts violently with alkali metals, strong bases and powdered metals.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, strong bases, and reactive metals.

10.6 Hazardous decomposition products

Hazardous decomposition products Poisonous gases, including phosgene, chlorine, and hydrogen chloride are produced in fire.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 250-800 mg/kg; LD50 Rabbit dermal 3990-8140 mg/kg; LD50 Mouse subcutaneous 1108 mg/kg

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1702

UN-No. (IMDG) UN 1702

UN-No. (IATA) UN 1702

UN-No. (ADN) UN 1702

UN-No. (RID) UN 1702

14.2 UN proper shipping name

Proper Shipping Name (ADR) 1,1,2,2-Tetrachloroethane

Proper Shipping Name (IMDG) 1,1,2,2-Tetrachloroethane

Proper Shipping Name (IATA) 1,1,2,2-Tetrachloroethane

Proper Shipping Name (ADN) 1,1,2,2-Tetrachloroethane

Proper Shipping Name (RID) 1,1,2,2-Tetrachloroethane

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.