Tetramethylammonium chloride
Synonyms: TMAC, N,N,N-Trimethylmethanaminium chloride
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Tetramethylammonium chloride
Product Form
Substance
Catalogue No.
AL4501
CAS Number
75-57-0
EC Number
200-880-8
EC Index Number
615-001-00-8
Grade
For Synthesis
HSN Code
29239000
Molecular Formula
C4H12ClN
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Tetramethylammonium chloride
Catalogue No.
AL4501
Product form
Substance
CAS Number
75-57-0
EC Number
200-880-8
Grade
For Synthesis
EC Index Number
615-001-00-8
Chemical Formula
C4H12ClN
HSN Code
29239000
Synonyms
TMAC, N,N,N-Trimethylmethanaminium chloride
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used as a phase-transfer catalyst and in organic synthesis.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 2; Acute Tox. 3; Skin Irrit. 2
Classification source
ECHA C&L Inventory via PubChem CID 6379 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Acute Toxic
Signal word
Danger
Hazard statements
H300: Fatal if swallowed; H311: Toxic in contact with skin; H315: Causes skin irritation
2.3 Other hazards
Other hazards
May cause respiratory irritation; handle in a well-ventilated area.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Tetramethylammonium chloride
CAS No.
75-57-0
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do; continue rinsing. Seek medical attention if irritation persists.
First-aid measures after ingestion
Rinse mouth. Do not induce vomiting. Seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Symptoms of exposure may include irritation of the skin, eyes, and respiratory tract.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Toxic fumes may be released in a fire. Use appropriate fire-fighting measures.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Contain spill and prevent entry into waterways. Wear appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water. Personal protection: P3 filter respirator for toxic particles.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Avoid contact with skin and eyes. Use personal protective equipment as required.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Separated from oxidants. Dry. Well closed.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
White
Odour
Odourless
Odour threshold
Not applicable
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
420 °C (decomposes)
Freezing point
Not applicable
Boiling point
Not applicable
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not applicable
Flammability (solid, gas)
Not flammable
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.1690 at 20 °C/4 °C
Solubility
Slightly soluble in ethanol; insoluble in ether, benzene, chloroform; very soluble in methanol
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions; avoid strong oxidizing agents.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes above 300 °C . This produces ammonia, carbon monoxide, hydrogen chloride and nitrogen oxides. Reacts with oxidants.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizing agents, strong acids.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits very toxic fumes of nitrogen oxides, ammonia and hydrogen chloride.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Mouse sc 40 mg/kg; LD50 Mouse ip 25 mg/kg
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 2811
UN-No. (IMDG)
UN 2811
UN-No. (IATA)
UN 2811
UN-No. (ADN)
UN 2811
UN-No. (RID)
UN 2811
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Toxic solid, organic, n.o.s.
Proper Shipping Name (IMDG)
Toxic solid, organic, n.o.s.
Proper Shipping Name (IATA)
Toxic solid, organic, n.o.s.
Proper Shipping Name (ADN)
Toxic solid, organic, n.o.s.
Proper Shipping Name (RID)
Toxic solid, organic, n.o.s.
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.