Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Toluene

Product Form Substance

Catalogue No. AL4595

CAS Number 108-88-3

EC Number 203-625-9

EC Index Number 601-021-00-3

Grade AR

HSN Code 29023000

Molecular Formula C7H8

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Toluene

Catalogue No. AL4595

Product form Substance

CAS Number 108-88-3

EC Number 203-625-9

Grade AR

EC Index Number 601-021-00-3

Chemical Formula C7H8

HSN Code 29023000

Synonyms Methylbenzene, Toluol

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Solvent, reagent in chemical synthesis

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 2; Asp. Tox. 1; Skin Irrit. 2; STOT SE 3; Repr. 2; STOT RE 2

Classification source ECHA C&L Inventory via PubChem CID 1140 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Flammable, Irritant, Health Hazard

Signal word Danger

Hazard statements H225: Highly Flammable liquid and vapor; H304: May be fatal if swallowed and enters airways; H315: Causes skin irritation; H336: May cause drowsiness or dizziness; H361: Suspected of damaging fertility or the unborn child; H373: May causes damage to organs through prolonged or repeated exposure

2.3 Other hazards

Other hazards May cause drowsiness or dizziness.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Toluene

CAS No. 108-88-3

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, respiratory irritation.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Poisonous gases may be produced in fire.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area. Remove all sources of ignition. Ventilate area.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Evacuate danger area! Consult an expert! Personal protection: chemical protection suit and self-contained breathing apparatus. Ventilation. Remove all ignition sources. Do NOT wash away into sewer.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use in a well-ventilated area. Avoid contact with skin and eyes. Keep away from heat and open flames.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Well closed. Fireproof. Separated from strong oxidants. Store in an area without drain or sewer access. Store only in original container.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Handle with gloves.

Eye protection Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless

Odour Sweet, pungent, benzene-like odor

Odour threshold 0.02 ppm

pH value Not applicable

Relative evaporation rate (butylacetate=1) 2.3

Melting point -94.9 °C

Freezing point Not applicable

Boiling point 110.6 °C

Flash point 4.0 °C (39.2 °F) - closed cup

Auto-ignition temperature 896 °F (480 °C)

Decomposition temperature Not available

Flammability (solid, gas) Flammable liquid

Vapour pressure 28.4 mm Hg at 25 °C

Relative vapour density at 20°C 3.1 (Air = 1)

Density 0.8623 g/cu cm at 20 °C

Solubility In water, 526 mg/L at 25 °C

Log Pow 2.73

Viscosity, kinematic 0.89 cSt at 20°C

Viscosity, dynamic 0.59 mPa·s at 20°C

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits 1.2 - 7.0 vol% in air

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Reacts with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Reacts violently with strong oxidants such as nitric acid and sulfuric acid. This generates fire and explosion hazard. This produces irritating and toxic gases.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, strong acids, and bases.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits acrid smoke and irritating fumes.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 2.6 to 7.5 g/kg; LD50 Rabbit dermal 14.1 mL/kg; LD50 Rat (female) ip 1.64 g/kg

Skin corrosion/irritation H315: Causes skin irritation

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) H336: May cause drowsiness or dizziness

Specific target organ toxicity (repeated exposure) H373: May causes damage to organs through prolonged or repeated exposure

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1294

UN-No. (IMDG) UN 1294

UN-No. (IATA) UN 1294

UN-No. (ADN) UN 1294

UN-No. (RID) UN 1294

14.2 UN proper shipping name

Proper Shipping Name (ADR) Toluene

Proper Shipping Name (IMDG) Toluene

Proper Shipping Name (IATA) Toluene

Proper Shipping Name (ADN) Toluene

Proper Shipping Name (RID) Toluene

14.3 Transport hazard class(es)

Transport hazard class(es) 3

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.