p-Toluidine
Synonyms: p-Aminotoluene, 4-Toluidine
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
p-Toluidine
Product Form
Substance
Catalogue No.
AL4618
CAS Number
106-49-0
EC Number
203-403-1
EC Index Number
612-002-00-7
Grade
99% For Synthesis
HSN Code
29214350
Molecular Formula
C7H9N
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
p-Toluidine
Catalogue No.
AL4618
Product form
Substance
CAS Number
106-49-0
EC Number
203-403-1
Grade
99% For Synthesis
EC Index Number
612-002-00-7
Chemical Formula
C7H9N
HSN Code
29214350
Synonyms
p-Aminotoluene, 4-Toluidine
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used as a synthetic intermediate in dye chemistry and pharmaceuticals.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 3; Skin Sens. 1; Eye Irrit. 2; Carc. 2; Aquatic Acute 1
Classification source
ECHA C&L Inventory via PubChem CID 7813 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Acute Toxic, Health Hazard, Environmental Hazard
Signal word
Danger
Hazard statements
H301: Toxic if swallowed; H311: Toxic in contact with skin; H317: May cause an allergic skin reaction; H319: Causes serious eye irritation; H331: Toxic if inhaled; H351: Suspected of causing cancer; H400: Very toxic to aquatic life
2.3 Other hazards
Other hazards
Suspected carcinogen; may cause skin and respiratory irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
p-Toluidine
CAS No.
106-49-0
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Headache, dizziness, nausea, skin irritation, respiratory distress.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
As a result of flow, agitation, etc., electrostatic charges can be generated.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use in a fume hood with appropriate PPE including gloves and goggles.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Provision to contain effluent from fire extinguishing. Separated from strong oxidants, strong acids and food and feedstuffs. Well closed. Ventilation along the floor. Keep in the dark. Store in an area without drain or sewer access.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
White to pale tan
Odour
Aromatic, wine-like odor
Odour threshold
No data available
pH value
No data available
Relative evaporation rate (butylacetate=1)
No data available
Melting point
43.6 °C
Freezing point
No data available
Boiling point
200.4 °C
Flash point
190 °F (88 °C) (closed cup)
Auto-ignition temperature
900 °F (482 °C)
Decomposition temperature
No data available
Flammability (solid, gas)
Flammable solid
Vapour pressure
VP: 1 mm Hg at 42 °C
Relative vapour density at 20°C
3.90 (Air = 1)
Density
0.9619 g/cu cm at 20 °C
Solubility
Very soluble in ethanol, pyridine; soluble in diethyl ether, acetone, carbon tetrachloride
Log Pow
1.39
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
No data available
Oxidising properties
No data available
Explosive limits
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions. Reacts with strong oxidizing agents.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on heating and on burning. This produces toxic fumes including nitrogen oxides. Reacts with strong oxidants and strong acids.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong acids.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits highly toxic fumes of nitroxides.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 656 mg/kg; LD50 Mouse oral 330 mg/kg; LD50 Rat male sc 1012 mg/kg bw
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
H319: Causes serious eye irritation
Respiratory or skin sensitisation
H317: May cause an allergic skin reaction
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
H351: Suspected of causing cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 3451
UN-No. (IMDG)
UN 3451
UN-No. (IATA)
UN 3451
UN-No. (ADN)
UN 3451
UN-No. (RID)
UN 3451
14.2 UN proper shipping name
Proper Shipping Name (ADR)
p-Toluidine
Proper Shipping Name (IMDG)
p-Toluidine
Proper Shipping Name (IATA)
p-Toluidine
Proper Shipping Name (ADN)
p-Toluidine
Proper Shipping Name (RID)
p-Toluidine
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.