Safety Data Sheet - Tributylamine

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Tributylamine

Product Form Substance

Catalogue No. AL4630

CAS Number 102-82-9

EC Number 203-058-7

EC Index Number 612-058-00-2

Grade 99% For Synthesis

HSN Code 29211990

Molecular Formula C12H27N

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Tributylamine

Catalogue No. AL4630

Product form Substance

CAS Number 102-82-9

EC Number 203-058-7

Grade 99% For Synthesis

EC Index Number 612-058-00-2

Chemical Formula C12H27N

HSN Code 29211990

Synonyms N,N-Dibutylamine, Tributylamine

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Used as a base catalyst and phase-transfer catalyst in organic synthesis.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 4; Acute Tox. 2; Skin Irrit. 2; Acute Tox. 1

Classification source ECHA C&L Inventory via PubChem CID 7622 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Acute Toxic

Signal word Danger

Hazard statements H302: Harmful if swallowed; H310: Fatal in contact with skin; H315: Causes skin irritation; H330: Fatal if inhaled

2.3 Other hazards

Other hazards Highly malodorous; may cause respiratory irritation.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Tributylamine

CAS No. 102-82-9

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Toxic effects may include respiratory distress, skin irritation, and eye irritation.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures The vapour is heavier than air.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Use appropriate protective equipment.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: filter respirator for ammonia and organic ammonia derivatives adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in sealable containers as far as possible. Cover the spilled material with inert absorbent.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Handle in a fume hood with appropriate personal protective equipment (PPE). Avoid contact with skin and eyes.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Dry. Separated from strong oxidants, strong acids and food and feedstuffs.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Handle with gloves.

Eye protection Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless to pale yellow

Odour Odor of ammonia

Odour threshold Not specified

pH value Not specified

Relative evaporation rate (butylacetate=1) Not specified

Melting point -70 °C

Freezing point Not specified

Boiling point 207 °C

Flash point 63 °C (145 °F) - closed cup

Auto-ignition temperature 210 °C

Decomposition temperature Not specified

Flammability (solid, gas) Not applicable

Vapour pressure 9.34X10-2 mm Hg at 25 °C

Relative vapour density at 20°C 6.39 (Air = 1)

Density 0.7782 at 20 °C/20 °C

Solubility In water, 142 mg/L at 25 °C

Log Pow 4.46

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not specified

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions, but may react with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on burning. This produces toxic gases including nitrogen oxides. The substance is a weak base.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, acids, and bases.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomp, emits toxic fumes of nitrogen oxides.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LC50 Rat, inhalation 500 mgcu m air4 hr; LD50 Rabbit, dermal 195 mg/kg bw; LD50 Rats, i.p. 107 mg/kg bw

Skin corrosion/irritation H315: Causes skin irritation

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 2542

UN-No. (IMDG) UN 2542

UN-No. (IATA) UN 2542

UN-No. (ADN) UN 2542

UN-No. (RID) UN 2542

14.2 UN proper shipping name

Proper Shipping Name (ADR) Tributylamine

Proper Shipping Name (IMDG) Tributylamine

Proper Shipping Name (IATA) Tributylamine

Proper Shipping Name (ADN) Tributylamine

Proper Shipping Name (RID) Tributylamine

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.