Safety Data Sheet - Trichloroethylene

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Trichloroethylene

Product Form Substance

Catalogue No. AL5035

CAS Number 79-01-6

EC Number 201-167-4

EC Index Number 602-007-00-0

Grade 99% Purified

HSN Code 29032200

Molecular Formula C2HCl3

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Trichloroethylene

Catalogue No. AL5035

Product form Substance

CAS Number 79-01-6

EC Number 201-167-4

Grade 99% Purified

EC Index Number 602-007-00-0

Chemical Formula C2HCl3

HSN Code 29032200

Synonyms Trichloroethene, TCE

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Solvent, degreasing agent

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Skin Irrit. 2; Eye Irrit. 2; STOT SE 3; Muta. 2; Carc. 1B; Aquatic Chronic 3

Classification source ECHA C&L Inventory via PubChem CID 6575 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Irritant, Health Hazard

Signal word Danger

Hazard statements H315: Causes skin irritation; H319: Causes serious eye irritation; H336: May cause drowsiness or dizziness; H341: Suspected of causing genetic defects; H350: May cause cancer; H412: Harmful to aquatic life with long lasting effects

2.3 Other hazards

Other hazards Known human carcinogen; may cause reproductive toxicity.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Trichloroethylene

CAS No. 79-01-6

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, respiratory distress, skin irritation.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Vapors are heavier than air and will collect in low areas. Vapors may travel long distances to ignition sources and flashback.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area. Ventilate. Contain spill and absorb with inert material.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance and complete protective clothing. Ventilation. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use in a fume hood. Wear appropriate PPE including gloves and goggles.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from metals, strong bases, food and feedstuffs, combustible substances and ignition sources. See Chemical Dangers. Dry. Keep in the dark. Keep in a well-ventilated room. Cool.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Handle with gloves.

Eye protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection Wear suitable protective clothing

Respiratory protection Use NIOSH-approved respirators when exposure limits may be exceeded.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless

Odour Ethereal odor

Odour threshold Not established

pH value Not applicable

Relative evaporation rate (butylacetate=1) >1

Melting point -84.7 °C

Freezing point Not applicable

Boiling point 87.2 °C

Flash point greater than 200 °F

Auto-ignition temperature 420 °C (788 °F)

Decomposition temperature Not established

Flammability (solid, gas) Not flammable

Vapour pressure 69 mm Hg at 25 °C

Relative vapour density at 20°C 4.53 (Air = 1)

Density 1.4642 at 20 °C/4 °C

Solubility In water, range of 999-1,472 mgL at 25 °C (average of 1,118 mgL) 7 measured values

Log Pow 2.61

Viscosity, kinematic Not established

Viscosity, dynamic Not established

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not applicable

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Reacts with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on contact with hot surfaces or flames. This produces toxic and corrosive fumes of phosgene and hydrogen chloride. Decomposes on contact with strong alkali.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, strong bases, and reactive metals.

10.6 Hazardous decomposition products

Hazardous decomposition products Hazardous decomposition products formed under fire conditions - Carbon oxides, hydrogen chloride gas.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 7161 mg/kg; LD50 Mouse (female) oral 2443 mg/kg; LD50 Mouse (male) oral 2402 mg/kg

Skin corrosion/irritation H315: Causes skin irritation

Serious eye damage/irritation H319: Causes serious eye irritation

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity H341: Suspected of causing genetic defects

Carcinogenicity H350: May cause cancer

Specific target organ toxicity (single exposure) H336: May cause drowsiness or dizziness

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 1710

UN-No. (IMDG) 1710

UN-No. (IATA) 1710

UN-No. (ADN) 1710

UN-No. (RID) 1710

14.2 UN proper shipping name

Proper Shipping Name (ADR) Trichloroethylene

Proper Shipping Name (IMDG) Trichloroethylene

Proper Shipping Name (IATA) Trichloroethylene

Proper Shipping Name (ADN) Trichloroethylene

Proper Shipping Name (RID) Trichloroethylene

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.