2,4,6-Trichlorophenol
Synonyms: Trichlorophenol, TCP
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
2,4,6-Trichlorophenol
Product Form
Substance
Catalogue No.
AL4640
CAS Number
88-06-2
EC Number
201-795-9
EC Index Number
602-097-00-9
Grade
98%
HSN Code
29081900
Molecular Formula
C6H3Cl3O
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
2,4,6-Trichlorophenol
Catalogue No.
AL4640
Product form
Substance
CAS Number
88-06-2
EC Number
201-795-9
Grade
98%
EC Index Number
602-097-00-9
Chemical Formula
C6H3Cl3O
HSN Code
29081900
Synonyms
Trichlorophenol, TCP
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Intermediate in pesticide and wood preservative synthesis
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4; Skin Irrit. 2; Eye Irrit. 2; Carc. 2; Aquatic Acute 1; Aquatic Chronic 1
Classification source
ECHA C&L Inventory via PubChem CID 6914 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Irritant, Health Hazard, Environmental Hazard
Signal word
Warning
Hazard statements
H302: Harmful if swallowed; H315: Causes skin irritation; H319: Causes serious eye irritation; H351: Suspected of causing cancer; H400: Very toxic to aquatic life; H410: Very toxic to aquatic life with long lasting effects
Precautionary statements
P203, P264, P264+P265, P270, P273, P280, P301+P317, P302+P352, P305+P351+P338, P318, P321, P330, P332+P317, P337+P317, P362+P364, P391, P405, P501
2.3 Other hazards
Other hazards
Suspected carcinogen; may cause skin and eye irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
2,4,6-Trichlorophenol
CAS No.
88-06-2
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
May cause respiratory irritation, skin irritation, and eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Special hazards arising from the substance or mixture: Carbon oxides, hydrogen chloride gas.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use personal protective equipment. Avoid contact with skin and eyes. Ensure adequate ventilation.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Provision to contain effluent from fire extinguishing. Separated from strong oxidants and food and feedstuffs. Well closed. Store in an area without drain or sewer access.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
White to pale yellow
Odour
Strong phenolic odor
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
69.5 °C
Freezing point
Not specified
Boiling point
249 °C
Flash point
99 °C c.c.
Auto-ignition temperature
Not specified
Decomposition temperature
Not specified
Flammability (solid, gas)
Flammable solid
Vapour pressure
0.008 mm Hg at 25 °C
Relative vapour density at 20°C
Not specified
Density
1.4901
Solubility
In water, 500 mg/L at 25 °C
Log Pow
3.69
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions; avoid strong oxidizing agents.
10.2 Chemical stability
Chemical stability
Stable up to its melting point.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on heating. This produces toxic and corrosive fumes including hydrogen chloride and chlorine. Reacts with strong oxidants.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizing agents, strong bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits toxic fumes of hydrogen chloride.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 2.8 g/kg; LD50 Rat oral 820 mg/kg; LD50 RAT ip 276 mg/kg
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
H319: Causes serious eye irritation
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
H351: Suspected of causing cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
3077
UN-No. (IMDG)
3077
UN-No. (IATA)
3077
UN-No. (ADN)
3077
UN-No. (RID)
3077
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Environmentally hazardous substance, solid, n.o.s.
Proper Shipping Name (IMDG)
Environmentally hazardous substance, solid, n.o.s.
Proper Shipping Name (IATA)
Environmentally hazardous substance, solid, n.o.s.
Proper Shipping Name (ADN)
Environmentally hazardous substance, solid, n.o.s.
Proper Shipping Name (RID)
Environmentally hazardous substance, solid, n.o.s.
14.3 Transport hazard class(es)
Transport hazard class(es)
9
14.4 Packing group
Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.