4-Fluoroaniline
- CAS Number
- 371-40-4
- HSN Code
- 29214190
- Molecular Formula
- C6H6FN
- Catalogue Number
- AL2206
- Purity
- ≥ 98%
- Molecular Weight
- 111.12 g/mol
Complies with : IP | BP | USP | EP | ACS
ISO 9001
ISO 14001
GMP
COA with every batch
Key Properties
4-fluoroaniline is a primary arylamine that is the derivative of aniline in which the hydrogen at position 4 has been substituted by fluorine. It is used as an intermediate in the manufacture of pharmaceuticals, herbicides and plant growth regulators.
Also known as p-Fluoroaniline.
- Catalogue No.
- AL2206
- CAS Number
- 371-40-4
- Molecular Formula
- C6H6FN
- Molecular Weight
- 111.12 g/mol
- HSN Code
- 29214190
- Grade
- 98%
- Product Form
- Substance
Melting point: -1.9 °C; Boiling point: 188 °C; Flash point: 74 °C; Density: 1.1725 at 20 °C/4 °C; Solubility: In water, 33 g/L at 20 °C.
- Appearance
- Liquid
- Shelf Life
- -
- Packaging
- Available in: 100 ml glass bottle, 500 ml glass bottle with tin cap
- Storage
- Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
1.1 — Product identifier
- Chemical Name
- 4-Fluoroaniline
- Catalogue No.
- AL2206
- Product form
- Substance
- CAS Number
- 371-40-4
- EC Number
- 206-735-5
- Grade
- 98%
- EC Index Number
- 612-005-00-5
- Chemical Formula
- C6H6FN
- HSN Code
- 29214190
- Synonyms
- p-Fluoroaniline
1.2 — Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture
- Synthetic intermediate in pharmaceutical and agrochemical synthesis.
- Uses advised against
- Not specified
1.3 — Details of the supplier of the safety data sheet
- Company identification
- Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 — Emergency Contact Details
- Phone / e-Mail
- Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
2.1 — Classification of the substance or mixture
- Classification according to Regulation (EC) No 1272/2008
- Acute Tox. 4; Skin Corr. 1C; Eye Dam. 1; STOT RE 2; Aquatic Acute 1; Aquatic Chronic 1
- Classification source
- ECHA C&L Inventory via PubChem CID 9731 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 — Label elements
- Hazard pictograms
- Corrosive, Irritant, Health Hazard, Environmental Hazard
- Signal word
- Danger
- Hazard statements
- H302: Harmful if swallowed; H314: Causes severe skin burns and eye damage; H318: Causes serious eye damage; H373: May causes damage to organs through prolonged or repeated exposure; H400: Very toxic to aquatic life; H410: Very toxic to aquatic life with long lasting effects
- Precautionary statements
- P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P363, P391, P405, P501
2.3 — Other hazards
- Other hazards
- May cause respiratory irritation.
3.1 — Substance
- Name
- 4-Fluoroaniline
- CAS No.
- 371-40-4
4.1 — Description of first aid measures
- First-aid measures after inhalation
- Remove victim from exposure immediately; if needed, administer oxygen; refer to physician.
- First-aid measures after skin contact
- Remove victim from exposure immediately; remove contaminated clothing; wash contacted area with copious amounts of water and soap; if needed, administer oxygen; refer to physician.
- First-aid measures after eye contact
- Flush with water for at least 15 min.
- First-aid measures after ingestion
- Induce vomiting; get medical attention.
4.2 — Most important symptoms and effects, both acute and delayed
- Symptoms relating to use
- Toxic effects may include headache, dizziness, and respiratory distress.
4.3 — Indication of any immediate medical attention and special treatment needed
- General information
- Treat symptomatically. Show this safety data sheet to the treating physician.
5.1 — Extinguishing media
- Suitable extinguishing media
- For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Special protective equipment for firefighters: Wear self contained breathing apparatus for fire fighting if necessary.
- Unsuitable extinguishing media
- Not specified
5.2 — Special hazards arising from the substance or mixture
- Special procedures
- Toxic fumes may be released in a fire. Use water spray to cool containers.
5.3 — Advice for firefighters
- Protection during firefighting
- Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1 — For non-emergency personnel
- Emergency procedures
- Evacuate area. Wear appropriate protective equipment. Contain and collect spillage.
6.3 — Methods and material for containment and cleaning up
- Methods for cleaning up
- Absorb spillage with inert material and dispose of in accordance with local regulations.
6.4 — Reference to other sections
- Reference
- Not specified
7.1 — Precautions for safe handling
- Precautions for safe handling
- Handle under fume hood. Use gloves and protective eyewear.
- Hygiene measures
- Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 — Conditions for safe storage, including any incompatibilities
- Storage conditions
- Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
8.2 — Exposure controls
- Hand protection
- Protective gloves (e.g. nitrile rubber)
- Eye protection
- Chemical safety goggles or safety glasses
- Skin and body protection
- Wear suitable protective clothing
- Respiratory protection
- Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.
9.1 — Information on basic physical and chemical properties
- Physical state
- Liquid
- Colour
- Colorless to pale yellow
- Odour
- Aromatic
- Odour threshold
- Not specified
- pH value
- Not specified
- Relative evaporation rate (butylacetate=1)
- Not specified
- Melting point
- -1.9 °C
- Freezing point
- Not specified
- Boiling point
- 188 °C
- Flash point
- 74 °C
- Auto-ignition temperature
- Not specified
- Decomposition temperature
- Not specified
- Flammability (solid, gas)
- Not flammable
- Vapour pressure
- 0.75 mm Hg (1 hectoPa) at 20 °C
- Relative vapour density at 20°C
- Not specified
- Density
- 1.1725 at 20 °C/4 °C
- Solubility
- In water, 33 g/L at 20 °C
- Log Pow
- 1.15
- Viscosity, kinematic
- Not specified
- Viscosity, dynamic
- Not specified
- Explosive properties
- Not explosive
- Oxidising properties
- Not oxidizing
- Explosive limits
- Not specified
10.1 — Reactivity
- Reactivity
- Stable under normal conditions. Reacts with strong oxidizing agents.
10.2 — Chemical stability
- Chemical stability
- Stable under recommended storage conditions.
10.3 — Possibility of hazardous reactions
- Possibility of hazardous reactions
- No dangerous reactions known under normal conditions of use.
10.4 — Conditions to avoid
- Conditions to avoid
- Avoid contact with incompatible materials and excessive heat.
10.5 — Incompatible materials
- Incompatible materials
- Strong oxidizing agents, strong acids.
10.6 — Hazardous decomposition products
- Hazardous decomposition products
- When heated to decomposition it emits very toxic fumes of nitrogen oxides and hydrogen fluoride.
11.1 — Information on toxicological effects
- Acute toxicity
- LD50 Rat oral 417 mg/kg
- Skin corrosion/irritation
- H314: Causes severe skin burns and eye damage
- Serious eye damage/irritation
- H318: Causes serious eye damage
- Respiratory or skin sensitisation
- Not classified (based on available data)
- Germ cell mutagenicity
- Not classified (based on available data)
- Carcinogenicity
- Not classified (based on available data)
- Specific target organ toxicity (single exposure)
- Not classified (based on available data)
- Specific target organ toxicity (repeated exposure)
- H373: May causes damage to organs through prolonged or repeated exposure
12.1 — Toxicity
- Toxicity information
- Not specified
12.2 — Persistence - degradability
- Persistence - degradability
- Not specified
12.3 — Bioaccumulative potential
- Bioaccumulative potential
- Not specified
12.4 — Mobility in soil
- Mobility in soil
- Not specified
12.6 — Other adverse effects
- Environmental precautions
- Not specified
13.1 — Waste treatment methods
- Additional Info
- Dispose of contents/container in accordance with local, regional, national and international regulations.
14.1 — UN number
- UN-No. (ADR)
- UN 2941
- UN-No. (IMDG)
- UN 2941
- UN-No. (IATA)
- UN 2941
- UN-No. (ADN)
- UN 2941
- UN-No. (RID)
- UN 2941
14.2 — UN proper shipping name
- Proper Shipping Name (ADR)
- 4-Fluoroaniline
- Proper Shipping Name (IMDG)
- 4-Fluoroaniline
- Proper Shipping Name (IATA)
- 4-Fluoroaniline
- Proper Shipping Name (ADN)
- 4-Fluoroaniline
- Proper Shipping Name (RID)
- 4-Fluoroaniline
14.3 — Transport hazard class(es)
- Transport hazard class(es)
- 6.1
14.4 — Packing group
- Packing group (ADR)
- III
- Packing group (IMDG)
- III
- Packing group (IATA)
- III
- Packing group (ADN)
- III
- Packing group (RID)
- III
14.5 — Environmental hazards
- Dangerous for the environment
- Not specified
- Marine pollutant
- Not specified
- Other information
- No supplementary information available
15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture
- 15.1.1 EU-Regulations
- Not specified
Intermediate in manufacture of herbicides and plant growth regulators.
ISO 9001
ISO 14001
GMP
COA with every batch
- Batch Number
- AL-2026-AL0748C
- Manufacturing Date
- September-2026
- Expiry Date
- September-2031
- Molecular Weight
- 111.12 g/mol
| Test | Standard | Observed |
|---|---|---|
| Description | Yellow to brown colored liquid | brown colored liquid |
| Assay (GC) | Min. 98.0% | 98.47% |
| d 20 o4 o | 1.157-1.159 | 1.1574 |
| B.P. | About 187°C | 187°C |
The above product complies with LR grade
Technical Data Sheet
| Grade | Assay/Purity | Melting/Boiling Point | Moisture/LOD | Residue on Ignition | Related Substances | Solubility |
|---|---|---|---|---|---|---|
| 98% | ≥ 98% | m.p. -1.9 °C; b.p. 188 °C | ≤ 0.5% | ≤ 0.1% | None detected | In water, 33 g/L at 20 °C |
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