Allyl bromide
- CAS Number
- 106-95-6
- HSN Code
- 29033990
- Molecular Formula
- C3H5Br
- Catalogue Number
- AL0175
- Purity
- ≥ 98%
- Molecular Weight
- 120.98 g/mol
Complies with : IP | BP | USP | EP | ACS
ISO 9001
ISO 14001
GMP
COA with every batch
Key Properties
Allyl bromide appears as a clear colorless to light yellow liquid with an irritating unpleasant odor. Flash point 30 °F. Irritates eyes, skin, and respiratory system.
Also known as 3-Bromopropene.
- Catalogue No.
- AL0175
- CAS Number
- 106-95-6
- Molecular Formula
- C3H5Br
- Molecular Weight
- 120.98 g/mol
- HSN Code
- 29033990
- Grade
- 98%
- Product Form
- Substance
Melting point: -119 °C; Boiling point: 71.3 °C at 760 mm Hg; Flash point: 30 °F (-1 °C); Density: 1.398 at 20 °C/4 °C; Solubility: Miscible with alcohol, chloroform, ether, carbon disulfide, carbon tetrachloride.
- Appearance
- Colorless to light yellow liquid
- Shelf Life
- 12 months
- Packaging
- Available in: 250 ml glass bottle with tin cap, 500 ml glass bottle with tin cap
- Storage
- Separate from oxidizing materials, alkalies. Store in cool, dry, well-ventilated location.
1.1 — Product identifier
- Chemical Name
- Allyl bromide
- Catalogue No.
- AL0175
- Product form
- Substance
- CAS Number
- 106-95-6
- EC Number
- 203-446-6
- Grade
- 98%
- EC Index Number
- 603-058-00-2
- Chemical Formula
- C3H5Br
- HSN Code
- 29033990
- Synonyms
- 3-Bromopropene
1.2 — Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture
- Allylating agent in organic synthesis
- Uses advised against
- Not specified
1.3 — Details of the supplier of the safety data sheet
- Company identification
- Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 — Emergency Contact Details
- Phone / e-Mail
- Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
2.1 — Classification of the substance or mixture
- Classification according to Regulation (EC) No 1272/2008
- Flam. Liq. 2; Acute Tox. 3; Skin Corr. 1B; Aquatic Acute 1
- Classification source
- ECHA C&L Inventory via PubChem CID 7841 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 — Label elements
- Hazard pictograms
- Flammable, Corrosive, Acute Toxic, Environmental Hazard
- Signal word
- Danger
- Hazard statements
- H225: Highly Flammable liquid and vapor; H301: Toxic if swallowed; H314: Causes severe skin burns and eye damage; H331: Toxic if inhaled; H400: Very toxic to aquatic life
2.3 — Other hazards
- Other hazards
- Highly flammable and toxic; may cause respiratory irritation.
3.1 — Substance
- Name
- Allyl bromide
- CAS No.
- 106-95-6
4.1 — Description of first aid measures
- First-aid measures after inhalation
- Remove from exposure; if not breathing, give artificial respiration; if breathing is difficult, give oxygen; call physician.
- First-aid measures after skin contact
- Flush with water; get medical attention for skin irritation.
- First-aid measures after eye contact
- Flush with water for at least 15 min. and call physician.
- First-aid measures after ingestion
- Do NOT induce vomiting; get medical attention.
4.2 — Most important symptoms and effects, both acute and delayed
- Symptoms relating to use
- Irritation of the skin, eyes, and respiratory tract; headache; nausea; vomiting.
4.3 — Indication of any immediate medical attention and special treatment needed
- General information
- Treat symptomatically. Show this safety data sheet to the treating physician.
5.1 — Extinguishing media
- Suitable extinguishing media
- Water spray, carbon dioxide, dry chemical powder, foam.
- Unsuitable extinguishing media
- Not specified
5.2 — Special hazards arising from the substance or mixture
- Special procedures
- Vapors are heavier than air and may travel to a source of ignition and flash back.
5.3 — Advice for firefighters
- Protection during firefighting
- Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1 — For non-emergency personnel
- Emergency procedures
- Evacuate area. Remove all sources of ignition. Ventilate area.
6.3 — Methods and material for containment and cleaning up
- Methods for cleaning up
- Contain spill with inert material. Collect and dispose of in accordance with local regulations.
6.4 — Reference to other sections
- Reference
- Not specified
7.1 — Precautions for safe handling
- Precautions for safe handling
- Use in a fume hood. Wear appropriate personal protective equipment (PPE). Avoid contact with skin and eyes.
- Hygiene measures
- Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 — Conditions for safe storage, including any incompatibilities
- Storage conditions
- Separate from oxidizing materials, alkalies. Store in cool, dry, well-ventilated location.
8.2 — Exposure controls
- Hand protection
- Protective gloves (e.g. nitrile rubber)
- Eye protection
- Chemical safety goggles or safety glasses
- Skin and body protection
- Wear suitable protective clothing
- Respiratory protection
- Use appropriate respiratory protection if ventilation is inadequate.
9.1 — Information on basic physical and chemical properties
- Physical state
- Liquid
- Colour
- Colorless to pale yellow
- Odour
- Unpleasant, pungent
- Odour threshold
- Not specified
- pH value
- Not applicable
- Relative evaporation rate (butylacetate=1)
- Not specified
- Melting point
- -119 °C
- Freezing point
- Not specified
- Boiling point
- 71.3 °C at 760 mm Hg
- Flash point
- 30 °F (-1 °C)
- Auto-ignition temperature
- 563 °F (295 °C)
- Decomposition temperature
- Not specified
- Flammability (solid, gas)
- Highly flammable liquid
- Vapour pressure
- Not specified
- Relative vapour density at 20°C
- 4.17 (Air = 1)
- Density
- 1.398 at 20 °C/4 °C
- Solubility
- Miscible with alcohol, chloroform, ether, carbon disulfide, carbon tetrachloride
- Log Pow
- 1.79
- Viscosity, kinematic
- Not specified
- Viscosity, dynamic
- Not specified
- Explosive properties
- Not explosive
- Oxidising properties
- Not oxidizing
- Explosive limits
- Not specified
10.1 — Reactivity
- Reactivity
- Reacts with strong oxidizing agents and bases.
10.2 — Chemical stability
- Chemical stability
- Stable under recommended storage conditions.
10.3 — Possibility of hazardous reactions
- Possibility of hazardous reactions
- No dangerous reactions known under normal conditions of use.
10.4 — Conditions to avoid
- Conditions to avoid
- Avoid contact with incompatible materials and excessive heat.
10.5 — Incompatible materials
- Incompatible materials
- Strong oxidizing agents, strong bases, and amines.
10.6 — Hazardous decomposition products
- Hazardous decomposition products
- When heated to decomposition it emits toxic fumes of hydrogen bromide.
11.1 — Information on toxicological effects
- Acute toxicity
- LD50 Guinea pig oral 30 mg/kg; LC50 Rat inhalation 10000 mgcu m30 min; LD50 Mouse ip 108 mg/kg
- Skin corrosion/irritation
- H314: Causes severe skin burns and eye damage
- Serious eye damage/irritation
- Not classified (based on available data)
- Respiratory or skin sensitisation
- Not classified (based on available data)
- Germ cell mutagenicity
- Not classified (based on available data)
- Carcinogenicity
- Not classified (based on available data)
- Specific target organ toxicity (single exposure)
- Not classified (based on available data)
- Specific target organ toxicity (repeated exposure)
- Not classified (based on available data)
12.1 — Toxicity
- Toxicity information
- Not specified
12.2 — Persistence - degradability
- Persistence - degradability
- Not specified
12.3 — Bioaccumulative potential
- Bioaccumulative potential
- Not specified
12.4 — Mobility in soil
- Mobility in soil
- Not specified
12.6 — Other adverse effects
- Environmental precautions
- Not specified
13.1 — Waste treatment methods
- Additional Info
- Dispose of contents/container in accordance with local, regional, national and international regulations.
14.1 — UN number
- UN-No. (ADR)
- UN 1099
- UN-No. (IMDG)
- UN 1099
- UN-No. (IATA)
- UN 1099
- UN-No. (ADN)
- UN 1099
- UN-No. (RID)
- UN 1099
14.2 — UN proper shipping name
- Proper Shipping Name (ADR)
- Allyl bromide
- Proper Shipping Name (IMDG)
- Allyl bromide
- Proper Shipping Name (IATA)
- Allyl bromide
- Proper Shipping Name (ADN)
- Allyl bromide
- Proper Shipping Name (RID)
- Allyl bromide
14.3 — Transport hazard class(es)
- Transport hazard class(es)
- 3 (6.1)
14.4 — Packing group
- Packing group (ADR)
- I
- Packing group (IMDG)
- I
- Packing group (IATA)
- I
- Packing group (ADN)
- I
- Packing group (RID)
- I
14.5 — Environmental hazards
- Dangerous for the environment
- Not specified
- Marine pollutant
- Not specified
- Other information
- No supplementary information available
15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture
- 15.1.1 EU-Regulations
- Not specified
Used as an allylating agent in the synthesis of pharmaceuticals, agrochemicals, and fine chemicals.
ISO 9001
ISO 14001
GMP
COA with every batch
- Batch Number
- AL-2026-AL00042
- Manufacturing Date
- September-2026
- Expiry Date
- September-2031
- Molecular Weight
- 120.98 g/mol
| Test | Standard | Observed |
|---|---|---|
| Description | Almost colourless to brownish yellow coloured liquid. | Almost colourless to brownish yellow coloured liquid. |
| Assay (GC) | Min. 98.0% | 98.56% |
| D 20°/ 4° | 1.427 - 1.430 | 1.4272 |
| Refractive index | 1.469 - 1.470 | 1.469 |
The above product complies with LR grade
Technical Data Sheet
| Grade | Assay/Purity | Melting/Boiling Point | Moisture/LOD | Residue on Ignition | Related Substances | Solubility |
|---|---|---|---|---|---|---|
| 98% | ≥ 98% | m.p. -119 °C; b.p. 71.3 °C at 760 mm Hg | ≤ 0.5% | Not applicable | Not more than 2% | Miscible with alcohol, chloroform, ether, carbon disulfide, carbon tetrachloride |
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