Dimethyl Malonate
- CAS Number
- 105-53-3
- HSN Code
- 29171990
- Molecular Formula
- C7H12O4
- Catalogue Number
- AL1853
- Purity
- ≥ 99%
- Molecular Weight
- 160.17 g/mol
Complies with : IP | BP | USP | EP | ACS
ISO 9001
ISO 14001
GMP
COA with every batch
Key Properties
Ethyl malonate is a dicarboxylic acid.
Also known as Dimethyl malonate, Dimethyl malonic acid ester.
- Catalogue No.
- AL1853
- CAS Number
- 105-53-3
- Molecular Formula
- C7H12O4
- Molecular Weight
- 160.17 g/mol
- HSN Code
- 29171990
- Grade
- 99% For Synthesis
- Product Form
- Substance
Melting point: -50 °C; Boiling point: 200 °C; Flash point: 200 °F (93 °C) (open cup); Density: 1.0551 g/cu cm at 20 °C; Solubility: In water, 20 g/L at 20 °C.
- Appearance
- Colorless liquid
- Shelf Life
- 2 years
- Packaging
- Available in: 500 ml glass bottle
- Storage
- Separated from strong oxidants. Ventilation along the floor. Store in an area without drain or sewer access.
1.1 — Product identifier
- Chemical Name
- Dimethyl Malonate
- Catalogue No.
- AL1853
- Product form
- Substance
- CAS Number
- 105-53-3
- EC Number
- 203-305-9
- Grade
- 99% For Synthesis
- EC Index Number
- 607-115-00-0
- Chemical Formula
- C7H12O4
- HSN Code
- 29171990
- Synonyms
- Dimethyl malonate, Dimethyl malonic acid ester
1.2 — Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture
- Used as a reagent in organic synthesis.
- Uses advised against
- Not specified
1.3 — Details of the supplier of the safety data sheet
- Company identification
- Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 — Emergency Contact Details
- Phone / e-Mail
- Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
2.1 — Classification of the substance or mixture
- Classification according to Regulation (EC) No 1272/2008
- Eye Irrit. 2A
- Classification source
- ECHA C&L Inventory via PubChem CID 7761 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 — Label elements
- Hazard pictograms
- Irritant
- Signal word
- Warning
- Hazard statements
- H319: Causes serious eye irritation
- Precautionary statements
- P264+P265, P280, P305+P351+P338, P337+P317
2.3 — Other hazards
- Other hazards
- May cause skin and eye irritation.
3.1 — Substance
- Name
- Dimethyl Malonate
- CAS No.
- 105-53-3
4.1 — Description of first aid measures
- First-aid measures after inhalation
- Move to fresh air. If symptoms persist, seek medical attention.
- First-aid measures after skin contact
- Wash with soap and water. If irritation occurs, seek medical attention.
- First-aid measures after eye contact
- Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
- First-aid measures after ingestion
- Rinse mouth. Do not induce vomiting. Seek medical attention if symptoms occur.
4.2 — Most important symptoms and effects, both acute and delayed
- Symptoms relating to use
- Irritation of eyes, skin, and respiratory tract.
4.3 — Indication of any immediate medical attention and special treatment needed
- General information
- Treat symptomatically. Show this safety data sheet to the treating physician.
5.1 — Extinguishing media
- Suitable extinguishing media
- Water spray, carbon dioxide, dry chemical powder, foam.
- Unsuitable extinguishing media
- Not specified
5.2 — Special hazards arising from the substance or mixture
- Special procedures
- Combustible liquid; may produce toxic fumes in a fire.
5.3 — Advice for firefighters
- Protection during firefighting
- Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1 — For non-emergency personnel
- Emergency procedures
- Evacuate area and ventilate. Contain spill and absorb with inert material.
6.3 — Methods and material for containment and cleaning up
- Methods for cleaning up
- Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent.
6.4 — Reference to other sections
- Reference
- Not specified
7.1 — Precautions for safe handling
- Precautions for safe handling
- Avoid contact with skin and eyes. Use in a well-ventilated area.
- Hygiene measures
- Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 — Conditions for safe storage, including any incompatibilities
- Storage conditions
- Separated from strong oxidants. Ventilation along the floor. Store in an area without drain or sewer access.
8.2 — Exposure controls
- Hand protection
- Handle with gloves.
- Eye protection
- Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
- Skin and body protection
- Impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
- Respiratory protection
- Use appropriate respiratory protection if ventilation is inadequate.
9.1 — Information on basic physical and chemical properties
- Physical state
- Liquid
- Colour
- Colorless
- Odour
- Sweet ester odor
- Odour threshold
- No data available
- pH value
- No data available
- Relative evaporation rate (butylacetate=1)
- No data available
- Melting point
- -50 °C
- Freezing point
- No data available
- Boiling point
- 200 °C
- Flash point
- 200 °F (93 °C) (open cup)
- Auto-ignition temperature
- 435 °C
- Decomposition temperature
- No data available
- Flammability (solid, gas)
- Not applicable
- Vapour pressure
- 0.19 mm Hg at 25 °C
- Relative vapour density at 20°C
- 5.52 (Air = 1)
- Density
- 1.0551 g/cu cm at 20 °C
- Solubility
- In water, 20 g/L at 20 °C
- Log Pow
- 0.96
- Viscosity, kinematic
- No data available
- Viscosity, dynamic
- No data available
- Explosive properties
- Not explosive
- Oxidising properties
- Not oxidizing
- Explosive limits
- No data available
10.1 — Reactivity
- Reactivity
- Stable under normal conditions. Reacts with strong oxidizing agents.
10.2 — Chemical stability
- Chemical stability
- Stable under recommended storage conditions.
10.3 — Possibility of hazardous reactions
- Possibility of hazardous reactions
- It reacts with strong oxidants. This generates fire and explosion hazard.
10.4 — Conditions to avoid
- Conditions to avoid
- Avoid contact with incompatible materials and excessive heat.
10.5 — Incompatible materials
- Incompatible materials
- Strong oxidizing agents, strong acids.
10.6 — Hazardous decomposition products
- Hazardous decomposition products
- Hazardous decomposition products formed under fire conditions. - Carbon oxides.
11.1 — Information on toxicological effects
- Acute toxicity
- LD50 Rat oral 15 g/kg; LD50 Rat oral 15,794 mg/kg bw; LD50 Mice oral 6400 mg/kg
- Skin corrosion/irritation
- Not classified (based on available data)
- Serious eye damage/irritation
- H319: Causes serious eye irritation
- Respiratory or skin sensitisation
- Not classified (based on available data)
- Germ cell mutagenicity
- Not classified (based on available data)
- Carcinogenicity
- Not classified (based on available data)
- Specific target organ toxicity (single exposure)
- Not classified (based on available data)
- Specific target organ toxicity (repeated exposure)
- Not classified (based on available data)
12.1 — Toxicity
- Toxicity information
- Not specified
12.2 — Persistence - degradability
- Persistence - degradability
- Not specified
12.3 — Bioaccumulative potential
- Bioaccumulative potential
- Not specified
12.4 — Mobility in soil
- Mobility in soil
- Not specified
12.6 — Other adverse effects
- Environmental precautions
- Not specified
13.1 — Waste treatment methods
- Additional Info
- Dispose of contents/container in accordance with local, regional, national and international regulations.
14.1 — UN number
- UN-No. (ADR)
- Not assigned
- UN-No. (IMDG)
- Not assigned
- UN-No. (IATA)
- Not assigned
- UN-No. (ADN)
- Not assigned
- UN-No. (RID)
- Not assigned
14.2 — UN proper shipping name
- Proper Shipping Name (ADR)
- Dimethyl Malonate
- Proper Shipping Name (IMDG)
- Dimethyl Malonate
- Proper Shipping Name (IATA)
- Dimethyl Malonate
- Proper Shipping Name (ADN)
- Dimethyl Malonate
- Proper Shipping Name (RID)
- Dimethyl Malonate
14.3 — Transport hazard class(es)
- Transport hazard class(es)
- Not classified as hazardous
14.4 — Packing group
- Packing group (ADR)
- Not applicable
- Packing group (IMDG)
- Not applicable
- Packing group (IATA)
- Not applicable
- Packing group (ADN)
- Not applicable
- Packing group (RID)
- Not applicable
14.5 — Environmental hazards
- Dangerous for the environment
- Not specified
- Marine pollutant
- Not specified
- Other information
- No supplementary information available
15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture
- 15.1.1 EU-Regulations
- Not specified
Used in malonic-ester-type synthesis reactions for preparing substituted acetic acids and heterocycles.
ISO 9001
ISO 14001
GMP
COA with every batch
- Batch Number
- AL-2026-AL0632H
- Manufacturing Date
- September-2026
- Expiry Date
- September-2031
- Molecular Weight
- 160.17 g/mol
| Test | Standard | Observed |
|---|---|---|
| Assay | ≥ 99% | 99.5% |
| Density | 1.156 g/mL | 1.156 g/mL |
| Boiling Point | 199 °C | 199 °C |
| Moisture Content | ≤ 0.5% | 0.3% |
| Residue on Ignition | ≤ 0.1% | 0.05% |
| Related Substances | None detected | None detected |
The above product is expected to comply with 99% For Synthesis grade specification.
Technical Data Sheet
| Grade | Assay/Purity | Melting/Boiling Point | Moisture/LOD | Residue on Ignition | Related Substances | Solubility |
|---|---|---|---|---|---|---|
| 99% For Synthesis | ≥ 99% | m.p. -50 °C; b.p. 200 °C | ≤ 0.5% | ≤ 0.1% | None detected | In water, 20 g/L at 20 °C |
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“From ordering to shipping, every course of action was smooth. Timely delivery.”
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