m-Anisidine

97% For Laboratory Use
CAS Number
536-90-3
HSN Code
29221990
Molecular Formula
C7H9NO
Catalogue Number
AL0447
Purity
≥ 97%
Molecular Weight
123.16 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Pale yellow, oily liquid
Shelf Life -
Packaging Available in: 100 ml glass bottle, 500 ml glass bottle
Storage Well closed. Separated from food and feedstuffs and strong oxidants.

3-Methoxyaniline is an aromatic ether and a substituted aniline.

Also known as 3-Methoxyaniline.

Catalogue No.
AL0447
CAS Number
536-90-3
Molecular Formula
C7H9NO
Molecular Weight
123.16 g/mol
HSN Code
29221990
Grade
97%
Product Form
Substance

Melting point: -1 °C; Boiling point: 251 °C; Flash point: 126 °C (259 °F) - closed cup; Density: 1.1 g/cm³; Solubility: Slightly soluble in carbon tetrachloride; soluble in ethanol, ethylene, acetone, benzene.

Appearance
Pale yellow, oily liquid
Shelf Life
-
Packaging
Available in: 100 ml glass bottle, 500 ml glass bottle
Storage
Well closed. Separated from food and feedstuffs and strong oxidants.

1.1 — Product identifier

Chemical Name
m-Anisidine
Catalogue No.
AL0447
Product form
Substance
CAS Number
536-90-3
EC Number
208-651-4
Grade
97%
EC Index Number
612-005-00-4
Chemical Formula
C7H9NO
HSN Code
29221990
Synonyms
3-Methoxyaniline

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Intermediate in dye and pharmaceutical synthesis.
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4; Skin Irrit. 2; Eye Irrit. 2; STOT SE 3; Aquatic Acute 1; Aquatic Chronic 1
Classification source
ECHA C&L Inventory via PubChem CID 10824 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Irritant, Environmental Hazard
Signal word
Warning
Hazard statements
H302: Harmful if swallowed; H315: Causes skin irritation; H319: Causes serious eye irritation; H335: May cause respiratory irritation; H400: Very toxic to aquatic life; H410: Very toxic to aquatic life with long lasting effects

2.3 — Other hazards

Other hazards
May cause respiratory irritation and skin sensitization.

3.1 — Substance

Name
m-Anisidine
CAS No.
536-90-3

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Toxic effects may include headache, dizziness, and respiratory distress.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Toxic fumes may be released in a fire. Use appropriate fire-fighting measures.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle with gloves and in a fume hood. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Well closed. Separated from food and feedstuffs and strong oxidants.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Pale yellow to amber
Odour
Aromatic
Odour threshold
Not specified
pH value
Not specified
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-1 °C
Freezing point
Not specified
Boiling point
251 °C
Flash point
126 °C (259 °F) - closed cup
Auto-ignition temperature
515 °C
Decomposition temperature
Not specified
Flammability (solid, gas)
Not applicable
Vapour pressure
7.5X10-2 mm Hg at 25 °C
Relative vapour density at 20°C
Not specified
Density
1.1 g/cm³
Solubility
Slightly soluble in carbon tetrachloride; soluble in ethanol, ethylene, acetone, benzene
Log Pow
0.93
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified

10.1 — Reactivity

Reactivity
Stable under normal conditions, but may react with strong oxidizing agents.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
On combustion, forms toxic fumes including nitrogen oxides. Reacts with strong oxidants. This generates fire hazard.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong oxidizing agents, strong acids.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
LD50 Rat male and female oral 526 mg/kg
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
H319: Causes serious eye irritation
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
H335: May cause respiratory irritation
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 2431
UN-No. (IMDG)
UN 2431
UN-No. (IATA)
UN 2431
UN-No. (ADN)
UN 2431
UN-No. (RID)
UN 2431

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
m-Anisidine
Proper Shipping Name (IMDG)
m-Anisidine
Proper Shipping Name (IATA)
m-Anisidine
Proper Shipping Name (ADN)
m-Anisidine
Proper Shipping Name (RID)
m-Anisidine

14.3 — Transport hazard class(es)

Transport hazard class(es)
6.1

14.4 — Packing group

Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Anisidines are used in the manufacture of azo dyes, pharmaceuticals, textile-processing chemicals.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01826
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
123.16 g/mol
Test Standard Observed
Assay ≥ 97% 98.5%
Density 1.096-1.101 g/mL 1.099 g/mL
Boiling Point 198 °C 198 °C
Moisture Content ≤ 0.5% 0.3%
Residue on Ignition ≤ 0.1% 0.05%
Related Substances None detected None detected

The above product is expected to comply with 97% grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
97% ≥ 97% m.p. -1 °C; b.p. 251 °C ≤ 0.5% ≤ 0.1% None detected Slightly soluble in carbon tetrachloride; soluble in ethanol, ethylene, acetone, benzene
View full Technical Data Sheet

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