Methyl Benzoate
- CAS Number
- 93-58-3
- HSN Code
- 29163130
- Molecular Formula
- C8H8O2
- Catalogue Number
- AL3023
- Purity
- ≥ 99%
- Molecular Weight
- 136.15 g/mol
Complies with : IP | BP | USP | EP | ACS
ISO 9001
ISO 14001
GMP
COA with every batch
Key Properties
Methyl benzoate is a benzoate ester obtained by condensation of benzoic acid and methanol. It has a role as an insect attractant and a metabolite.
Also known as Benzoic acid methyl ester.
- Catalogue No.
- AL3023
- CAS Number
- 93-58-3
- Molecular Formula
- C8H8O2
- Molecular Weight
- 136.15 g/mol
- HSN Code
- 29163130
- Grade
- 99% For Synthesis
- Product Form
- Substance
Melting point: -12.35 °C; Boiling point: 199 °C; Flash point: 181 °F (83 °C) (Closed cup); Density: 1.0837 g/cu cm at 25 °C; Solubility: In water, 2100 mg/L at 20 °C.
- Appearance
- Colorless, transparent liquid
- Shelf Life
- 2 years
- Packaging
- Available in: 500 ml glass bottle, 2.5 Lt glass bottle
- Storage
- Store only in original container. Well closed. Ventilation along the floor.
1.1 — Product identifier
- Chemical Name
- Methyl Benzoate
- Catalogue No.
- AL3023
- Product form
- Substance
- CAS Number
- 93-58-3
- EC Number
- 202-259-7
- Grade
- 99% For Synthesis
- EC Index Number
- 607-095-00-7
- Chemical Formula
- C8H8O2
- HSN Code
- 29163130
- Synonyms
- Benzoic acid methyl ester
1.2 — Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture
- Solvent, fragrance, flavoring agent
- Uses advised against
- Not specified
1.3 — Details of the supplier of the safety data sheet
- Company identification
- Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 — Emergency Contact Details
- Phone / e-Mail
- Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
2.1 — Classification of the substance or mixture
- Classification according to Regulation (EC) No 1272/2008
- Acute Tox. 4
- Classification source
- ECHA C&L Inventory via PubChem CID 7150 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 — Label elements
- Hazard pictograms
- Irritant
- Signal word
- Warning
- Hazard statements
- H302: Harmful if swallowed
- Precautionary statements
- P264, P270, P301+P317, P330, P501
2.3 — Other hazards
- Other hazards
- None identified
3.1 — Substance
- Name
- Methyl Benzoate
- CAS No.
- 93-58-3
4.1 — Description of first aid measures
- First-aid measures after inhalation
- Move to fresh air. If symptoms persist, seek medical attention.
- First-aid measures after skin contact
- IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
- First-aid measures after eye contact
- First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
- First-aid measures after ingestion
- Rinse mouth. Do not induce vomiting. Seek medical attention if symptoms occur.
4.2 — Most important symptoms and effects, both acute and delayed
- Symptoms relating to use
- May cause mild irritation to skin and eyes.
4.3 — Indication of any immediate medical attention and special treatment needed
- General information
- Treat symptomatically. Show this safety data sheet to the treating physician.
5.1 — Extinguishing media
- Suitable extinguishing media
- Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
- Unsuitable extinguishing media
- Not specified
5.2 — Special hazards arising from the substance or mixture
- Special procedures
- The vapour is heavier than air.
5.3 — Advice for firefighters
- Protection during firefighting
- Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1 — For non-emergency personnel
- Emergency procedures
- Evacuate area and ventilate. Contain spill and absorb with inert material.
6.3 — Methods and material for containment and cleaning up
- Methods for cleaning up
- Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
6.4 — Reference to other sections
- Reference
- Not specified
7.1 — Precautions for safe handling
- Precautions for safe handling
- Avoid contact with skin and eyes. Use in a well-ventilated area.
- Hygiene measures
- Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 — Conditions for safe storage, including any incompatibilities
- Storage conditions
- Store only in original container. Well closed. Ventilation along the floor.
8.2 — Exposure controls
- Hand protection
- Handle with gloves.
- Eye protection
- Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
- Skin and body protection
- Wear suitable protective clothing
- Respiratory protection
- Use appropriate respiratory protection if ventilation is inadequate.
9.1 — Information on basic physical and chemical properties
- Physical state
- Liquid
- Colour
- Colorless
- Odour
- Fragrant odor
- Odour threshold
- Not determined
- pH value
- Not applicable
- Relative evaporation rate (butylacetate=1)
- <1
- Melting point
- -12.35 °C
- Freezing point
- Not determined
- Boiling point
- 199 °C
- Flash point
- 181 °F (83 °C) (Closed cup)
- Auto-ignition temperature
- 542 °C
- Decomposition temperature
- Not determined
- Flammability (solid, gas)
- Not flammable
- Vapour pressure
- 0.38 mm Hg at 25 °C
- Relative vapour density at 20°C
- 4.69 (Air = 1)
- Density
- 1.0837 g/cu cm at 25 °C
- Solubility
- In water, 2100 mg/L at 20 °C
- Log Pow
- 2.12
- Viscosity, kinematic
- Not determined
- Viscosity, dynamic
- Not determined
- Explosive properties
- Not explosive
- Oxidising properties
- Not oxidizing
- Explosive limits
- Not applicable
10.1 — Reactivity
- Reactivity
- Stable under normal conditions.
10.2 — Chemical stability
- Chemical stability
- Stable under recommended storage conditions.
10.3 — Possibility of hazardous reactions
- Possibility of hazardous reactions
- On combustion, forms toxic gases of carbon monoxide (see ICSC 0023).
10.4 — Conditions to avoid
- Conditions to avoid
- Avoid contact with incompatible materials and excessive heat.
10.5 — Incompatible materials
- Incompatible materials
- Strong oxidizing agents, strong acids.
10.6 — Hazardous decomposition products
- Hazardous decomposition products
- When heated to decomposition, it emites fumes containing CO and CO2.
11.1 — Information on toxicological effects
- Acute toxicity
- LD50 (oral, rat) > 5000 mg/kg
- Skin corrosion/irritation
- Not classified (based on available data)
- Serious eye damage/irritation
- Not classified (based on available data)
- Respiratory or skin sensitisation
- Not classified (based on available data)
- Germ cell mutagenicity
- Not classified (based on available data)
- Carcinogenicity
- Not classified (based on available data)
- Specific target organ toxicity (single exposure)
- Not classified (based on available data)
- Specific target organ toxicity (repeated exposure)
- Not classified (based on available data)
12.1 — Toxicity
- Toxicity information
- Not specified
12.2 — Persistence - degradability
- Persistence - degradability
- Not specified
12.3 — Bioaccumulative potential
- Bioaccumulative potential
- Not specified
12.4 — Mobility in soil
- Mobility in soil
- Not specified
12.6 — Other adverse effects
- Environmental precautions
- Not specified
13.1 — Waste treatment methods
- Additional Info
- Dispose of contents/container in accordance with local, regional, national and international regulations.
14.1 — UN number
- UN-No. (ADR)
- Not assigned
- UN-No. (IMDG)
- Not assigned
- UN-No. (IATA)
- Not assigned
- UN-No. (ADN)
- Not assigned
- UN-No. (RID)
- Not assigned
14.2 — UN proper shipping name
- Proper Shipping Name (ADR)
- Methyl Benzoate
- Proper Shipping Name (IMDG)
- Methyl Benzoate
- Proper Shipping Name (IATA)
- Methyl Benzoate
- Proper Shipping Name (ADN)
- Methyl Benzoate
- Proper Shipping Name (RID)
- Methyl Benzoate
14.3 — Transport hazard class(es)
- Transport hazard class(es)
- Not classified
14.4 — Packing group
- Packing group (ADR)
- Not classified
- Packing group (IMDG)
- Not classified
- Packing group (IATA)
- Not classified
- Packing group (ADN)
- Not classified
- Packing group (RID)
- Not classified
14.5 — Environmental hazards
- Dangerous for the environment
- Not specified
- Marine pollutant
- Not specified
- Other information
- No supplementary information available
15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture
- 15.1.1 EU-Regulations
- Not specified
Used as a solvent and fragrance/flavor ingredient in perfumery and food-science formulation research.
ISO 9001
ISO 14001
GMP
COA with every batch
- Batch Number
- AL-2026-AL01014
- Manufacturing Date
- September-2026
- Expiry Date
- September-2031
- Molecular Weight
- 136.15 g/mol
| Test | Standard | Observed |
|---|---|---|
| Description | Almost clear colorless liquid | Almost clear colorless liquid |
| Assay | (Min.) 99.0% | 99.36% |
| Wt /ml at 20°C | 1.085 - 1.087g | 1.085g |
| Refractive index | 1.516 - 1.518 | 1.5169 |
| Acidity | <1ml N% | <1ml N% |
The above product complies with LR grade
Technical Data Sheet
| Grade | Assay/Purity | Melting/Boiling Point | Moisture/LOD | Residue on Ignition | Related Substances | Solubility |
|---|---|---|---|---|---|---|
| 99% For Synthesis | ≥ 99% | m.p. -12.35 °C; b.p. 199 °C | ≤ 0.5% | ≤ 0.1% | None detected | In water, 2100 mg/L at 20 °C |
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