Potassium nitrite

Extra Pure For Laboratory Use
CAS Number
7758-09-0
HSN Code
28342100
Molecular Formula
KNO2
Catalogue Number
AL3746
Purity
96% min
Molecular Weight
85.11 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White or slightly yellow granules or rods
Shelf Life 2 years
Packaging Available in: 500 gm plastic bottle, 5 Kg plastic bottle
Storage Fireproof. Provision to contain effluent from fire extinguishing. Separated from combustible substances, reducing agents and acids. Dry. Well closed.

Potassium nitrite is an inorganic potassium salt and an inorganic molecular entity. It has a role as an antihypertensive agent and an antimicrobial food preservative.

Also known as Nitrous acid, potassium salt.

Catalogue No.
AL3746
CAS Number
7758-09-0
Molecular Formula
KNO2
Molecular Weight
85.11 g/mol
HSN Code
28342100
Grade
Extra Pure
Product Form
Substance

Melting point: 441 °C with decomp starting at 350 °C; Boiling point: 537 °C (explodes); Density: 1.915; Solubility: 312 g/100g of water at 25 °C.

Appearance
White or slightly yellow granules or rods
Shelf Life
2 years
Packaging
Available in: 500 gm plastic bottle, 5 Kg plastic bottle
Storage
Fireproof. Provision to contain effluent from fire extinguishing. Separated from combustible substances, reducing agents and acids. Dry. Well closed.

1.1 — Product identifier

Chemical Name
Potassium nitrite
Catalogue No.
AL3746
Product form
Substance
CAS Number
7758-09-0
EC Number
231-832-4
Grade
Extra Pure
EC Index Number
007-001-00-1
Chemical Formula
KNO2
HSN Code
28342100
Synonyms
Nitrous acid, potassium salt

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a food preservative and in organic synthesis as a diazotization reagent.
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Ox. Sol. 2; Acute Tox. 3; Aquatic Acute 1
Classification source
ECHA C&L Inventory via PubChem CID 516910 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Oxidizer, Acute Toxic, Environmental Hazard
Signal word
Danger
Hazard statements
H272: May intensify fire; oxidizer; H301: Toxic if swallowed; H400: Very toxic to aquatic life

2.3 — Other hazards

Other hazards
Oxidizer; may cause fire or explosion in contact with combustible materials.

3.1 — Substance

Name
Potassium nitrite
CAS No.
7758-09-0

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Rinse mouth. Do not induce vomiting. Seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Symptoms of exposure may include headache, dizziness, nausea, and respiratory distress.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Evaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Avoid dust formation. Use appropriate protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. Carefully collect remainder.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle with care. Use gloves and protective eyewear. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Fireproof. Provision to contain effluent from fire extinguishing. Separated from combustible substances, reducing agents and acids. Dry. Well closed.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust is generated.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White to pale yellow
Odour
Faint, characteristic
Odour threshold
Not specified
pH value
~7
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
441 °C with decomp starting at 350 °C
Freezing point
Not specified
Boiling point
537 °C (explodes)
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not specified
Flammability (solid, gas)
Not flammable under normal conditions
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.915
Solubility
312 g/100g of water at 25 °C
Log Pow
Not specified
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Oxidizer
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions; may react with strong acids and bases.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
May explode on heating above 530 °C. Decomposes on contact with even weak acids. This produces toxic fumes of nitrogen oxides. The substance is a strong oxidant.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong bases, and reducing agents.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Upon decomposition it emits toxic fumes of potassium oxide.

11.1 — Information on toxicological effects

Acute toxicity
LD50 Rabbit oral 108 mg anion/kg; LC50 Mouse inhalation 85 gcu m2 hr
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 1488
UN-No. (IMDG)
UN 1488
UN-No. (IATA)
UN 1488
UN-No. (ADN)
UN 1488
UN-No. (RID)
UN 1488

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Potassium nitrite
Proper Shipping Name (IMDG)
Potassium nitrite
Proper Shipping Name (IATA)
Potassium nitrite
Proper Shipping Name (ADN)
Potassium nitrite
Proper Shipping Name (RID)
Potassium nitrite

14.3 — Transport hazard class(es)

Transport hazard class(es)
5.1

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Potassium nitrite is utilized in various applications across different industries. In the food industry, it serves as a preservative, particularly in cured meats, where it helps to inhibit the growth of harmful bacteria and maintain color. In the field of organic chemistry, it is employed as a diazotization reagent, facilitating the synthesis of azo compounds, which are important in dye manufacturing. Additionally, potassium nitrite is used in the production of fertilizers, as a corrosion inhibitor in cooling systems, and in the synthesis of pharmaceuticals. Its role as a reference compound in analytical chemistry further underscores its importance in research and quality control.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01255
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
85.11 g/mol
Test Standard Observed
Assay 96% min 96.5%
Moisture Content <1% 0.5%
Residue on Ignition <0.5% 0.3%
Related Substances None detected None detected
Solubility 200 g/L in water at 20 °C 205 g/L in water at 20 °C

The above product is expected to comply with Extra Pure grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
Extra Pure 96% min m.p. 441 °C with decomp starting at 350 °C; b.p. 537 °C (explodes) <1% <0.5% None detected 312 g/100g of water at 25 °C
View full Technical Data Sheet

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