Sodium Borohydride

98% For Laboratory Use
CAS Number
16940-66-2
HSN Code
28500010
Molecular Formula
NaBH4
Catalogue Number
AL4091
Purity
≥ 98%
Molecular Weight
37.83 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White to gray-white microcystalline powder or lumps
Shelf Life Stable under recommended storage conditions
Packaging Available in: 100 gm plastic bottle, 500 gm plastic bottle
Storage Dry. Well closed. Separated from strong acids, alcohols, powdered metals and water.

Sodium borohydride is an inorganic sodium salt and a metal tetrahydridoborate.

Also known as Sodium tetrahydroborate, Sodium boranide.

Catalogue No.
AL4091
CAS Number
16940-66-2
Molecular Formula
NaBH4
Molecular Weight
37.83 g/mol
HSN Code
28500010
Grade
98%
Product Form
Substance

Melting point: >400 °C (vacuum) (decomposes); Density: 1.074 g/cu cm (anhydrous material); Solubility: Soluble in "Cellosolve" ether.

Appearance
White to gray-white microcystalline powder or lumps
Shelf Life
Stable under recommended storage conditions
Packaging
Available in: 100 gm plastic bottle, 500 gm plastic bottle
Storage
Dry. Well closed. Separated from strong acids, alcohols, powdered metals and water.

1.1 — Product identifier

Chemical Name
Sodium Borohydride
Catalogue No.
AL4091
Product form
Substance
CAS Number
16940-66-2
EC Number
241-004-4
Grade
98%
EC Index Number
004-001-00-0
Chemical Formula
NaBH4
HSN Code
28500010
Synonyms
Sodium tetrahydroborate, Sodium boranide

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Reducing agent in organic synthesis
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Water-react. 1; Acute Tox. 3; Skin Corr. 1C; Eye Dam. 1
Classification source
ECHA C&L Inventory via PubChem CID 4311764 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Flammable, Corrosive, Acute Toxic
Signal word
Danger
Hazard statements
H260: In contact with water releases flammable gases which may ignite spontaneously; H301: Toxic if swallowed; H314: Causes severe skin burns and eye damage; H318: Causes serious eye damage

2.3 — Other hazards

Other hazards
Reacts with water to release flammable hydrogen gas

3.1 — Substance

Name
Sodium Borohydride
CAS No.
16940-66-2

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Do NOT induce vomiting; give dilute vinegar, lemon juice, milk, or olive oil; call a doctor.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Irritation of eyes, skin, and respiratory tract; potential for burns in contact with moisture.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Flammable hydrogen gas may be released upon contact with water or acids.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Avoid ignition sources. Use appropriate protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Remove all ignition sources. Personal protection: chemical protection suit and particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered dry, plastic containers. Carefully collect remainder.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle under inert atmosphere. Use appropriate personal protective equipment (PPE) including gloves and goggles.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Dry. Well closed. Separated from strong acids, alcohols, powdered metals and water.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust or vapors are generated.

9.1 — Information on basic physical and chemical properties

Physical state
Granular solid
Colour
White to gray
Odour
Odourless
Odour threshold
Not applicable
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
>400 °C (vacuum) (decomposes)
Freezing point
Not applicable
Boiling point
1000 °C (decomposes)
Flash point
Not applicable
Auto-ignition temperature
~220 °C
Decomposition temperature
400 °C
Flammability (solid, gas)
Flammable hydrogen gas released upon contact with water
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.074 g/cu cm (anhydrous material)
Solubility
Soluble in "Cellosolve" ether
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive under normal conditions
Oxidising properties
Not an oxidizer
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Reacts vigorously with water and acids, releasing flammable hydrogen gas.

10.2 — Chemical stability

Chemical stability
Anhydrous material is stable in dry air to 300 °C; decomposes slowly at 400 °C and rapidly at 500 °C.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
Decomposes on heating and on contact with acids, powdered metals, water and moisture. This produces flammable/explosive gas (hydrogen). The substance is a strong reducing agent.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, water, moisture.

10.6 — Hazardous decomposition products

Hazardous decomposition products
When heated to decomposition emits toxic fumes of sodium oxides.

11.1 — Information on toxicological effects

Acute toxicity
LD50 Rat oral 160 mg/kg bw; LD50 Rat ip 18 mg/kg
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 1426
UN-No. (IMDG)
UN 1426
UN-No. (IATA)
UN 1426
UN-No. (ADN)
UN 1426
UN-No. (RID)
UN 1426

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium Borohydride
Proper Shipping Name (IMDG)
Sodium Borohydride
Proper Shipping Name (IATA)
Sodium Borohydride
Proper Shipping Name (ADN)
Sodium Borohydride
Proper Shipping Name (RID)
Sodium Borohydride

14.3 — Transport hazard class(es)

Transport hazard class(es)
4.3

14.4 — Packing group

Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium borohydride is primarily used as a mild and selective reducing agent in organic synthesis, particularly for the reduction of aldehydes and ketones to alcohols. It is widely employed in the pharmaceutical industry for the synthesis of various drug compounds. Additionally, it finds applications in the production of specialty chemicals, in the reduction of metal ions in electroplating, and in the preparation of boron-containing compounds. Its ability to release hydrogen gas also makes it useful in hydrogen storage and generation applications.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01359
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
37.83 g/mol
Test Standard Observed
Assay ≥ 98% 98.5%
Moisture Content ≤ 0.5% 0.3%
Residue on Ignition ≤ 0.1% 0.05%
Related Substances None detected None detected
Solubility Soluble in water Soluble

The above product is expected to comply with 98% grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
98% ≥ 98% m.p. >400 °C (vacuum) (decomposes) ≤ 0.5% ≤ 0.1% None detected Soluble in "Cellosolve" ether
View full Technical Data Sheet

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