Sodium Dithionite

85% For Laboratory Use
CAS Number
7775-14-6
HSN Code
28311010
Molecular Formula
Na2S2O4
Catalogue Number
AL4133
Purity
≥ 85%
Molecular Weight
174.11 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White or grayish-white crystalline powder
Shelf Life 12 months
Packaging Available in: 500 gm plastic bottle
Storage Dry. Well closed. Separated from strong oxidants and acids. Store in an area without drain or sewer access.

Sodium dithionite is an inorganic sodium salt that is the disodium salt of dithionous acid. It has a role as a bleaching agent and a reducing agent.

Also known as Sodium Hydrosulfite.

Catalogue No.
AL4133
CAS Number
7775-14-6
Molecular Formula
Na2S2O4
Molecular Weight
174.11 g/mol
HSN Code
28311010
Grade
85%
Product Form
Substance

Melting point: 52 °C (decomposes); Flash point: about 100 °C (open cup); Density: 2.38 g/cu cm; Solubility: Slightly sol in alcohol; very soluble in water.

Appearance
White or grayish-white crystalline powder
Shelf Life
12 months
Packaging
Available in: 500 gm plastic bottle
Storage
Dry. Well closed. Separated from strong oxidants and acids. Store in an area without drain or sewer access.

1.1 — Product identifier

Chemical Name
Sodium Dithionite
Catalogue No.
AL4133
Product form
Substance
CAS Number
7775-14-6
EC Number
231-890-0
Grade
85%
EC Index Number
016-030-00-5
Chemical Formula
Na2S2O4
HSN Code
28311010
Synonyms
Sodium Hydrosulfite

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Reducing agent in textile dyeing and analytical chemistry
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Self-heat. 1; Acute Tox. 4
Classification source
ECHA C&L Inventory via PubChem CID 24489 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Flammable, Irritant
Signal word
Danger
Hazard statements
H251: Self-heating; may catch fire; H302: Harmful if swallowed

2.3 — Other hazards

Other hazards
Spontaneously combustible when moist; may release toxic gases upon decomposition.

3.1 — Substance

Name
Sodium Dithionite
CAS No.
7775-14-6

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Rinse mouth. Do not induce vomiting. Seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Irritation of the respiratory tract, skin, and eyes; potential for chemical burns.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
May ignite spontaneously in moist conditions; use dry chemical, foam, or carbon dioxide extinguishers.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Avoid moisture and heat sources.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. Carefully collect remainder.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Avoid contact with moisture and heat. Use appropriate personal protective equipment (PPE).
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Dry. Well closed. Separated from strong oxidants and acids. Store in an area without drain or sewer access.

8.2 — Exposure controls

Hand protection
The selected protective gloves have to satisfy the specifications of EU Directive 89686EEC and the standard EN 374 derived from it. Handle with gloves.
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White to pale gray
Odour
Faint sulfurous
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
52 °C (decomposes)
Freezing point
Not applicable
Boiling point
200°C (decomposes)
Flash point
about 100 °C (open cup)
Auto-ignition temperature
about 190 °C
Decomposition temperature
190°C
Flammability (solid, gas)
Spontaneously combustible when moist
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
2.38 g/cu cm
Solubility
Slightly sol in alcohol; very soluble in water
Log Pow
< -4.7
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not applicable
Oxidising properties
Not applicable
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Reacts with moisture and air, decomposing to release sulfur dioxide and other products.

10.2 — Chemical stability

Chemical stability
Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
Decomposes above 100 °C . This produces toxic fumes including sulfur oxides. The substance is a strong reducing agent. It reacts with oxidants.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong oxidizers, acids, and moisture.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
LD50 Rat oral approx 2500 mg/kg bw; LD50 Mouse ip 900 mg/kg bw
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 1384
UN-No. (IMDG)
UN 1384
UN-No. (IATA)
UN 1384
UN-No. (ADN)
UN 1384
UN-No. (RID)
UN 1384

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium Dithionite
Proper Shipping Name (IMDG)
Sodium Dithionite
Proper Shipping Name (IATA)
Sodium Dithionite
Proper Shipping Name (ADN)
Sodium Dithionite
Proper Shipping Name (RID)
Sodium Dithionite

14.3 — Transport hazard class(es)

Transport hazard class(es)
4.2

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium dithionite is extensively used in the textile industry as a reducing agent for vat dyeing processes, enabling the reduction of insoluble dyes to their soluble forms for application on fabrics. In addition to its role in textiles, it serves as an oxygen scavenger in various analytical chemistry applications, particularly in the preservation of samples and reagents sensitive to oxidation. Furthermore, sodium dithionite is employed in the food industry as a bleaching agent and in the paper industry for pulp bleaching. Its versatility makes it a valuable chemical in multiple sectors, including pharmaceuticals and environmental applications.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01374
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
174.11 g/mol
Test Standard Observed
Assay ≥ 85% 87%
Moisture Content ≤ 5% 3.2%
Residue on Ignition ≤ 1% 0.5%
Related Substances None detected None detected
Solubility 50 g/L in water at 20°C 52 g/L in water at 20°C

The above product is expected to comply with 85% grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
85% ≥ 85% m.p. 52 °C (decomposes) ≤ 5% ≤ 1% None detected Slightly sol in alcohol; very soluble in water
View full Technical Data Sheet

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