Sodium Metabisulfite

Extra Pure For Laboratory Use
CAS Number
7681-57-4
HSN Code
28321090
Molecular Formula
Na2S2O5
Catalogue Number
AL4194
Purity
96.5%
Molecular Weight
190.10 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White hexagonal crystals or powder
Shelf Life 2 years
Packaging Available in: 500 gm plastic bottle, 5 Kg plastic container
Storage Separated from acids, strong oxidants and food and feedstuffs. Well closed.

Sodium disulfite is an inorganic sodium salt composed of sodium and disulfite ions in a 2:1 ratio. It has a role as a food antioxidant.

Also known as Sodium disulfite, Sodium pyrosulfite.

Catalogue No.
AL4194
CAS Number
7681-57-4
Molecular Formula
Na2S2O5
Molecular Weight
190.10 g/mol
HSN Code
28321090
Grade
Extra Pure
Product Form
Substance

Melting point: greater than 302 °F (Decomposes); Density: Specific gravity: 1.4 at 25 °C/4 °C; Solubility: Freely soluble in water, glycerol; slightly soluble in alcohol.

Appearance
White hexagonal crystals or powder
Shelf Life
2 years
Packaging
Available in: 500 gm plastic bottle, 5 Kg plastic container
Storage
Separated from acids, strong oxidants and food and feedstuffs. Well closed.

1.1 — Product identifier

Chemical Name
Sodium Metabisulfite
Catalogue No.
AL4194
Product form
Substance
CAS Number
7681-57-4
EC Number
231-673-0
Grade
Extra Pure
EC Index Number
016-063-00-2
Chemical Formula
Na2S2O5
HSN Code
28321090
Synonyms
Sodium disulfite, Sodium pyrosulfite

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Antioxidant, preservative, reducing agent
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4; Eye Dam. 1
Classification source
ECHA C&L Inventory via PubChem CID 656671 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Corrosive, Irritant
Signal word
Danger
Hazard statements
H302: Harmful if swallowed; H318: Causes serious eye damage
Precautionary statements
P264, P264+P265, P270, P280, P301+P317, P305+P354+P338, P317, P330, P501

2.3 — Other hazards

Other hazards
Releases irritating sulfur dioxide gas upon decomposition.

3.1 — Substance

Name
Sodium Metabisulfite
CAS No.
7681-57-4

4.1 — Description of first aid measures

First-aid measures after inhalation
If a person breathes large amounts of this chemical, move the exposed person to fresh air at once.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Irritation of the respiratory tract, skin, and eyes; potential allergic reactions.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Poisonous gases are produced in fire including sulfur oxides.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Avoid dust formation. Use appropriate personal protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Personal protection: filter respirator for acid gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in covered non-metallic containers as far as possible. Absorb liquid in sand or inert absorbent. Wash away remainder with plenty of water.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Avoid contact with skin and eyes. Use in a well-ventilated area. Wear appropriate personal protective equipment.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Separated from acids, strong oxidants and food and feedstuffs. Well closed.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust or mist is generated.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White
Odour
In the presences of traces of water, it develops an odor of sulfur dioxide
Odour threshold
Not specified
pH value
4.5 (1% solution)
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
greater than 302 °F (Decomposes)
Freezing point
Not specified
Boiling point
190 °C (decomposes)
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not specified
Flammability (solid, gas)
Non-flammable
Vapour pressure
Not specified
Relative vapour density at 20°C
Not specified
Density
Specific gravity: 1.4 at 25 °C/4 °C
Solubility
Freely soluble in water, glycerol; slightly soluble in alcohol
Log Pow
-3.7
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions, but may react with strong acids and oxidizing agents.

10.2 — Chemical stability

Chemical stability
On exposure to air and moisture is slowly oxidized to sulfate.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
Decomposes on heating and on contact with acids. This produces sulfur oxides. The substance is a strong reducing agent.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong oxidizers.

10.6 — Hazardous decomposition products

Hazardous decomposition products
When heated to decomposition it emits toxic fumes of sulfur and sodium oxides.

11.1 — Information on toxicological effects

Acute toxicity
LD50 Rat dermal > 2000 mg/kg; LD50 Hamster iv 95 mg/kg bw; LD50 Rabbit iv 65 mg/kg bw
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium Metabisulfite
Proper Shipping Name (IMDG)
Sodium Metabisulfite
Proper Shipping Name (IATA)
Sodium Metabisulfite
Proper Shipping Name (ADN)
Sodium Metabisulfite
Proper Shipping Name (RID)
Sodium Metabisulfite

14.3 — Transport hazard class(es)

Transport hazard class(es)
Not classified as hazardous for transport

14.4 — Packing group

Packing group (ADR)
Not applicable
Packing group (IMDG)
Not applicable
Packing group (IATA)
Not applicable
Packing group (ADN)
Not applicable
Packing group (RID)
Not applicable

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium metabisulfite is primarily used as an antioxidant and preservative in the food and beverage industry, particularly in winemaking, where it helps to prevent oxidation and spoilage. It is also utilized in the preservation of dried fruits and vegetables, as well as in the production of certain pharmaceuticals and cosmetics. Additionally, it serves as a reducing agent in various chemical processes and is employed in water treatment to remove chlorine. Its versatility makes it a valuable compound in both industrial and laboratory settings.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01393
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
190.10 g/mol
Test Standard Observed
Assay 96.5% min 96.8%
Moisture Content < 1.0% 0.5%
Residue on Ignition < 0.5% 0.3%
Related Substances None detected None detected
Solubility 50 g/100 mL 52 g/100 mL (at 20 °C)

The above product is expected to comply with Extra Pure grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
Extra Pure 96.5% m.p. greater than 302 °F (Decomposes) < 1.0% < 0.5% None detected Freely soluble in water, glycerol; slightly soluble in alcohol
View full Technical Data Sheet

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