Sulfur monochloride

99% For Laboratory Use
CAS Number
10025-67-9
HSN Code
28129000
Molecular Formula
S2Cl2
Catalogue Number
AL4427
Purity
≥ 99%
Molecular Weight
135.0 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Light amber to yellowish red oily liquid
Shelf Life -
Packaging Available in: 500 ml glass bottle
Storage Separated from strong oxidants, peroxides, phosphorus oxides, organic compounds and food and feedstuffs. Cool. Dry. Well closed. Ventilation along the floor.

Sulfur monochloride appears as a yellow-red, oily, fuming liquid with a sharp odor. Contact or ingestion causes irritation or chemical burns to skin, eyes, and mucous membranes.

Also known as Disulfur dichloride.

Catalogue No.
AL4427
CAS Number
10025-67-9
Molecular Formula
S2Cl2
Molecular Weight
135.0 g/mol
HSN Code
28129000
Grade
99%
Product Form
Substance

Melting point: -77 °C; Boiling point: 137 °C; Flash point: 118 °C; Density: 1.6885 at 15.5 °C/15.5 °C; Solubility: Sol in alc, benzene, ether, carbon disulfide, carbon tetrachloride, oils.

Appearance
Light amber to yellowish red oily liquid
Shelf Life
-
Packaging
Available in: 500 ml glass bottle
Storage
Separated from strong oxidants, peroxides, phosphorus oxides, organic compounds and food and feedstuffs. Cool. Dry. Well closed. Ventilation along the floor.

1.1 — Product identifier

Chemical Name
Sulfur monochloride
Catalogue No.
AL4427
Product form
Substance
CAS Number
10025-67-9
EC Number
233-036-2
Grade
99%
EC Index Number
017-004-00-4
Chemical Formula
S2Cl2
HSN Code
28129000
Synonyms
Disulfur dichloride

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Vulcanizing and chlorinating reagent
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Acute Tox. 3; Skin Corr. 1A; Acute Tox. 4; Aquatic Acute 1
Classification source
ECHA C&L Inventory via PubChem CID 24807 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Corrosive, Acute Toxic, Environmental Hazard
Signal word
Danger
Hazard statements
H301: Toxic if swallowed; H314: Causes severe skin burns and eye damage; H332: Harmful if inhaled; H400: Very toxic to aquatic life

2.3 — Other hazards

Other hazards
Corrosive to metals; may cause severe skin burns and eye damage.

3.1 — Substance

Name
Sulfur monochloride
CAS No.
10025-67-9

4.1 — Description of first aid measures

First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Symptoms of exposure may include coughing, difficulty breathing, skin burns, and eye irritation.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Confined fires with high fuel loads of polyvinyl chloride, such as a fire in a vault with a high load of polyvinyl chloride-coated electrical wiring, may generate sufficient hydrogen chloride to cause irritation in fire fighters.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment. Contain and absorb spill with inert material.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Cautiously neutralize spilled liquid with mixture of dry soda ash and slaked lime.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle under inert gas. Use in a fume hood with appropriate PPE including gloves and goggles.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Separated from strong oxidants, peroxides, phosphorus oxides, organic compounds and food and feedstuffs. Cool. Dry. Well closed. Ventilation along the floor.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a NIOSH-approved respirator if exposure limits are exceeded.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Amber to red-brown
Odour
Suffocating odor
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-77 °C
Freezing point
Not specified
Boiling point
137 °C
Flash point
118 °C
Auto-ignition temperature
453 °F (234 °C)
Decomposition temperature
Not specified
Flammability (solid, gas)
Not flammable
Vapour pressure
10 mm Hg at 27.5 °C
Relative vapour density at 20°C
4.66 (Air = 1)
Density
1.6885 at 15.5 °C/15.5 °C
Solubility
Sol in alc, benzene, ether, carbon disulfide, carbon tetrachloride, oils
Log Pow
Not specified
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified

10.1 — Reactivity

Reactivity
Highly reactive with water and moisture, producing hydrochloric acid and sulfur dioxide.

10.2 — Chemical stability

Chemical stability
Stable at ambient temperature.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
Decomposes on heating and on burning. This produces toxic and corrosive fumes including hydrogen chloride, hydrogen sulfide and sulfur oxides. Reacts with peroxides, phosphorus oxides and some organic compounds.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Water, strong bases, and strong oxidizing agents.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Decomposes on contact with water to produce heat & toxic & corrosive fumes.

11.1 — Information on toxicological effects

Acute toxicity
Highly toxic; may cause severe respiratory irritation and systemic effects.
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 3390
UN-No. (IMDG)
UN 3390
UN-No. (IATA)
UN 3390
UN-No. (ADN)
UN 3390
UN-No. (RID)
UN 3390

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sulfur monochloride
Proper Shipping Name (IMDG)
Sulfur monochloride
Proper Shipping Name (IATA)
Sulfur monochloride
Proper Shipping Name (ADN)
Sulfur monochloride
Proper Shipping Name (RID)
Sulfur monochloride

14.3 — Transport hazard class(es)

Transport hazard class(es)
6.1 (8)

14.4 — Packing group

Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sulfur monochloride is widely used in the rubber industry as a vulcanizing agent, where it enhances the strength and elasticity of rubber products. In organic chemistry, it serves as a sulfurizing and chlorinating reagent, facilitating the introduction of sulfur and chlorine into organic molecules. This compound is also employed in the synthesis of various sulfur-containing compounds, which are important in pharmaceuticals and agrochemicals. Additionally, it finds applications in the production of specialty chemicals and in the formulation of certain pesticides, highlighting its versatility in industrial chemistry.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1492L
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
135.0 g/mol
Test Standard Observed
Assay ≥ 99% 99.5%
Density 1.668 g/mL 1.670 g/mL
Melting Point -80 °C -79.5 °C
Boiling Point 140 °C 139 °C
Moisture Content ≤ 0.5% 0.3%
Related Substances None detected None detected

The above product is expected to comply with 99% grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
99% ≥ 99% m.p. -77 °C; b.p. 137 °C ≤ 0.5% Not applicable None detected Sol in alc, benzene, ether, carbon disulfide, carbon tetrachloride, oils
View full Technical Data Sheet

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