Tri-n-butyl phosphate

99% For Laboratory Use
CAS Number
126-73-8
HSN Code
29199090
Molecular Formula
C12H27O4P
Catalogue Number
AL4632
Purity
≥ 99%
Molecular Weight
266.32 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Colorless to pale-yellow liquid
Shelf Life -
Packaging Available in: 500 ml glass bottle, 2.5 Lt glass bottle
Storage Store in an area without drain or sewer access. Separated from bases and strong oxidants.

Tributyl phosphate is a trialkyl phosphate that is the tributyl ester of phosphoric acid.

Also known as n-Butyl phosphate.

Catalogue No.
AL4632
CAS Number
126-73-8
Molecular Formula
C12H27O4P
Molecular Weight
266.32 g/mol
HSN Code
29199090
Grade
99%
Product Form
Substance

Melting point: Less than -80 °C; Boiling point: 289 °C (decomposes); Flash point: 146 °C (open cup); Density: 0.978 at 20 °C/20 °C; Solubility: In water, 280 mg/L at 25 °C.

Appearance
Colorless to pale-yellow liquid
Shelf Life
-
Packaging
Available in: 500 ml glass bottle, 2.5 Lt glass bottle
Storage
Store in an area without drain or sewer access. Separated from bases and strong oxidants.

1.1 — Product identifier

Chemical Name
Tri-n-butyl phosphate
Catalogue No.
AL4632
Product form
Substance
CAS Number
126-73-8
EC Number
204-800-2
Grade
99%
EC Index Number
015-011-00-4
Chemical Formula
C12H27O4P
HSN Code
29199090
Synonyms
n-Butyl phosphate

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Solvent extraction reagent, plasticizer
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4; Skin Irrit. 2; Carc. 2
Classification source
ECHA C&L Inventory via PubChem CID 31357 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Irritant, Health Hazard
Signal word
Warning
Hazard statements
H302: Harmful if swallowed; H315: Causes skin irritation; H351: Suspected of causing cancer

2.3 — Other hazards

Other hazards
None identified

3.1 — Substance

Name
Tri-n-butyl phosphate
CAS No.
126-73-8

4.1 — Description of first aid measures

First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
May cause mild irritation to skin and eyes.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Special hazards arising from the substance or mixture: Carbon oxides, Oxides of phosphorus.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Contain spill and prevent entry into waterways. Use appropriate personal protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable non-plastic containers. Absorb remaining liquid in sand or inert absorbent.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Avoid contact with skin and eyes. Use in a well-ventilated area.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in an area without drain or sewer access. Separated from bases and strong oxidants.

8.2 — Exposure controls

Hand protection
Handle with gloves.
Eye protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless to pale yellow
Odour
Odorless
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
Less than -80 °C
Freezing point
Not specified
Boiling point
289 °C (decomposes)
Flash point
146 °C (open cup)
Auto-ignition temperature
410 °C
Decomposition temperature
Not specified
Flammability (solid, gas)
Not applicable
Vapour pressure
1.13X10-3 mm Hg at 25 °C
Relative vapour density at 20°C
9.20 (Air = 1)
Density
0.978 at 20 °C/20 °C
Solubility
In water, 280 mg/L at 25 °C
Log Pow
4.00
Viscosity, kinematic
Not specified
Viscosity, dynamic
5.5 mPa·s at 20°C
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified

10.1 — Reactivity

Reactivity
Stable under normal conditions, but may react with strong oxidizing agents.

10.2 — Chemical stability

Chemical stability
Stable.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
Decomposes on burning. This produces toxic fumes including phosphorus oxides. Reacts with warm water.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong oxidizers, strong acids.

10.6 — Hazardous decomposition products

Hazardous decomposition products
When heated to decomposition it emits toxic fumes of phosphorous oxide (PO(x)).

11.1 — Information on toxicological effects

Acute toxicity
LD50 Mouse ip 100 - 200 mg/kg bw; LD50 Rat ip 251.2 mg/kg bw; LD50 Guninea pig dermal 9700 - 19,400 mg/kg bw
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
H351: Suspected of causing cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Not classified as dangerous goods
Proper Shipping Name (IMDG)
Not classified as dangerous goods
Proper Shipping Name (IATA)
Not classified as dangerous goods
Proper Shipping Name (ADN)
Not classified as dangerous goods
Proper Shipping Name (RID)
Not classified as dangerous goods

14.3 — Transport hazard class(es)

Transport hazard class(es)
Not applicable

14.4 — Packing group

Packing group (ADR)
Not applicable
Packing group (IMDG)
Not applicable
Packing group (IATA)
Not applicable
Packing group (ADN)
Not applicable
Packing group (RID)
Not applicable

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Tri-n-butyl phosphate is primarily used as an extraction solvent in the PUREX (Plutonium Uranium Recovery by EXtraction) process for nuclear fuel reprocessing, where it plays a crucial role in the separation of plutonium and uranium from fission products. Beyond its nuclear applications, TBP is also employed as a plasticizer in the production of plastics and resins, enhancing flexibility and durability. Additionally, it is utilized in the formulation of hydraulic fluids, lubricants, and as a reagent in various chemical syntheses. Its ability to dissolve a wide range of organic compounds makes it valuable in laboratory settings for solvent extraction and chromatography.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1536A
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
266.32 g/mol
Test Standard Observed
Assay ≥ 99% 99.5%
Density 0.979 g/mL 0.978 g/mL
Boiling Point 315°C 316°C
Flash Point 150°C 152°C
Moisture Content ≤ 0.5% 0.3%
Residue on Ignition ≤ 0.1% 0.05%
Related Substances None detected None detected

The above product is expected to comply with 99% grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
99% ≥ 99% m.p. Less than -80 °C; b.p. 289 °C (decomposes) ≤ 0.5% ≤ 0.1% None detected In water, 280 mg/L at 25 °C
View full Technical Data Sheet

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