2-Nitroanisole
- CAS Number
- 91-23-6
- HSN Code
- 29093012
- Molecular Formula
- C7H7NO3
- Catalogue Number
- AL3274
- Purity
- ≥ 98%
- Molecular Weight
- 153.14 g/mol
Complies with : IP | BP | USP | EP | ACS
ISO 9001
ISO 14001
GMP
COA with every batch
Key Properties
2-nitroanisole is a member of the class of 2-nitroanisoles that is anisole in which one of the hydrogens ortho to the methoxy group is replaced by a nitro group. It has a role as a carcinogenic agent.
Also known as 2-Nitro-1-methoxybenzene.
- Catalogue No.
- AL3274
- CAS Number
- 91-23-6
- Molecular Formula
- C7H7NO3
- Molecular Weight
- 153.14 g/mol
- HSN Code
- 29093012
- Grade
- 98% For Synthesis
- Product Form
- Substance
Melting point: 10.5 °C; Boiling point: 277 °C; 144 °C at 4 mm Hg; Flash point: 142 °C closed cup; Density: 1.2540 g/cu cm at 20 °C; Solubility: Miscible with ethanol, ethyl ether; soluble in carbon tetrachloride.
- Appearance
- Colorless to yellowish liquid
- Shelf Life
- -
- Packaging
- Available in: 500 ml glass bottle, 2.5 Lt glass bottle with tin cap
- Storage
- Well closed. Store only in original packaging. Ventilation along the floor. Dry.
1.1 — Product identifier
- Chemical Name
- 2-Nitroanisole
- Catalogue No.
- AL3274
- Product form
- Substance
- CAS Number
- 91-23-6
- EC Number
- 202-052-1
- Grade
- 98% For Synthesis
- EC Index Number
- 609-007-00-0
- Chemical Formula
- C7H7NO3
- HSN Code
- 29093012
- Synonyms
- 2-Nitro-1-methoxybenzene
1.2 — Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture
- Used as a synthetic intermediate in the production of dyes and agrochemicals.
- Uses advised against
- Not specified
1.3 — Details of the supplier of the safety data sheet
- Company identification
- Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 — Emergency Contact Details
- Phone / e-Mail
- Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
2.1 — Classification of the substance or mixture
- Classification according to Regulation (EC) No 1272/2008
- Acute Tox. 4; Carc. 1B
- Classification source
- ECHA C&L Inventory via PubChem CID 7048 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 — Label elements
- Hazard pictograms
- Irritant, Health Hazard
- Signal word
- Danger
- Hazard statements
- H302: Harmful if swallowed; H350: May cause cancer
- Precautionary statements
- P203, P264, P270, P280, P301+P317, P318, P330, P405, P501
2.3 — Other hazards
- Other hazards
- Toxic; may cause harm if inhaled or absorbed through the skin.
3.1 — Substance
- Name
- 2-Nitroanisole
- CAS No.
- 91-23-6
4.1 — Description of first aid measures
- First-aid measures after inhalation
- Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention if symptoms persist.
- First-aid measures after skin contact
- Wash with soap and water. Remove contaminated clothing. Seek medical attention if irritation develops.
- First-aid measures after eye contact
- Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention if irritation persists.
- First-aid measures after ingestion
- Do not induce vomiting. Rinse mouth. Seek medical attention immediately.
4.2 — Most important symptoms and effects, both acute and delayed
- Symptoms relating to use
- Symptoms of exposure may include headache, dizziness, nausea, and respiratory distress.
4.3 — Indication of any immediate medical attention and special treatment needed
- General information
- Treat symptomatically. Show this safety data sheet to the treating physician.
5.1 — Extinguishing media
- Suitable extinguishing media
- Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters: Wear self contained breathing apparatus for fire fighting if necessary.
- Unsuitable extinguishing media
- Not specified
5.2 — Special hazards arising from the substance or mixture
- Special procedures
- The vapour is heavier than air.
5.3 — Advice for firefighters
- Protection during firefighting
- Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1 — For non-emergency personnel
- Emergency procedures
- Evacuate area. Wear appropriate protective equipment. Contain and collect spillage.
6.3 — Methods and material for containment and cleaning up
- Methods for cleaning up
- Personal protection: chemical protection suit and filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent.
6.4 — Reference to other sections
- Reference
- Not specified
7.1 — Precautions for safe handling
- Precautions for safe handling
- Handle under a fume hood. Use appropriate personal protective equipment, including gloves and goggles.
- Hygiene measures
- Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 — Conditions for safe storage, including any incompatibilities
- Storage conditions
- Well closed. Store only in original packaging. Ventilation along the floor. Dry.
8.2 — Exposure controls
- Hand protection
- Handle with gloves. Eye protection: Face shield and safety glasses Skin and body protection: Choose body protection according to the amount and concentration of the dangerous substance at the work place.
- Eye protection
- Chemical safety goggles or safety glasses
- Skin and body protection
- Wear suitable protective clothing
- Respiratory protection
- Use a NIOSH-approved respirator if exposure limits are exceeded.
9.1 — Information on basic physical and chemical properties
- Physical state
- Liquid
- Colour
- Pale yellow
- Odour
- Characteristic
- Odour threshold
- Not specified
- pH value
- Not specified
- Relative evaporation rate (butylacetate=1)
- Not specified
- Melting point
- 10.5 °C
- Freezing point
- Not specified
- Boiling point
- 277 °C; 144 °C at 4 mm Hg
- Flash point
- 142 °C closed cup
- Auto-ignition temperature
- 464 °C
- Decomposition temperature
- Not specified
- Flammability (solid, gas)
- Not applicable
- Vapour pressure
- 3.6X10-3 mm Hg at 25 °C
- Relative vapour density at 20°C
- Relative vapor density (air = 1): 5.29
- Density
- 1.2540 g/cu cm at 20 °C
- Solubility
- Miscible with ethanol, ethyl ether; soluble in carbon tetrachloride
- Log Pow
- 1.73
- Viscosity, kinematic
- Not specified
- Viscosity, dynamic
- Not specified
- Explosive properties
- Not explosive
- Oxidising properties
- Not oxidizing
- Explosive limits
- Not specified
10.1 — Reactivity
- Reactivity
- Stable under normal conditions. Avoid strong oxidizing agents.
10.2 — Chemical stability
- Chemical stability
- Stable under recommended storage conditions.
10.3 — Possibility of hazardous reactions
- Possibility of hazardous reactions
- On combustion, forms toxic and corrosive fumes. Reacts violently with zinc and sodium hydroxide.
10.4 — Conditions to avoid
- Conditions to avoid
- Avoid contact with incompatible materials and excessive heat.
10.5 — Incompatible materials
- Incompatible materials
- Strong oxidizing agents, strong acids.
10.6 — Hazardous decomposition products
- Hazardous decomposition products
- When heated to decomposition it emits toxic fumes of nitrogen oxide.
11.1 — Information on toxicological effects
- Acute toxicity
- LD50 Rat oral 1980 mg/kg; LD50 Rat oral 740 mg/kg; LD50 Rat oral 874 mg/kg bw
- Skin corrosion/irritation
- Not classified (based on available data)
- Serious eye damage/irritation
- Not classified (based on available data)
- Respiratory or skin sensitisation
- Not classified (based on available data)
- Germ cell mutagenicity
- Not classified (based on available data)
- Carcinogenicity
- H350: May cause cancer
- Specific target organ toxicity (single exposure)
- Not classified (based on available data)
- Specific target organ toxicity (repeated exposure)
- Not classified (based on available data)
12.1 — Toxicity
- Toxicity information
- Not specified
12.2 — Persistence - degradability
- Persistence - degradability
- Not specified
12.3 — Bioaccumulative potential
- Bioaccumulative potential
- Not specified
12.4 — Mobility in soil
- Mobility in soil
- Not specified
12.6 — Other adverse effects
- Environmental precautions
- Not specified
13.1 — Waste treatment methods
- Additional Info
- Dispose of contents/container in accordance with local, regional, national and international regulations.
14.1 — UN number
- UN-No. (ADR)
- UN 2730
- UN-No. (IMDG)
- UN 2730
- UN-No. (IATA)
- UN 2730
- UN-No. (ADN)
- UN 2730
- UN-No. (RID)
- UN 2730
14.2 — UN proper shipping name
- Proper Shipping Name (ADR)
- 2-Nitroanisole
- Proper Shipping Name (IMDG)
- 2-Nitroanisole
- Proper Shipping Name (IATA)
- 2-Nitroanisole
- Proper Shipping Name (ADN)
- 2-Nitroanisole
- Proper Shipping Name (RID)
- 2-Nitroanisole
14.3 — Transport hazard class(es)
- Transport hazard class(es)
- 6.1
14.4 — Packing group
- Packing group (ADR)
- III
- Packing group (IMDG)
- III
- Packing group (IATA)
- III
- Packing group (ADN)
- III
- Packing group (RID)
- III
14.5 — Environmental hazards
- Dangerous for the environment
- Not specified
- Marine pollutant
- Not specified
- Other information
- No supplementary information available
15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture
- 15.1.1 EU-Regulations
- Not specified
O-Isomer as dye intermediate; in organic syntheses.
ISO 9001
ISO 14001
GMP
COA with every batch
- Batch Number
- AL-2026-AL2458A
- Manufacturing Date
- September-2026
- Expiry Date
- September-2031
- Molecular Weight
- 153.14 g/mol
| Test | Standard | Observed |
|---|---|---|
| Assay | ≥ 98% | 98.5% |
| Moisture Content | ≤ 0.5% | 0.3% |
| Density | 1.254 g/mL | 1.254 g/mL |
| Related Substances | Not specified | No significant impurities detected |
The above product is expected to comply with 98% For Synthesis grade specification.
Technical Data Sheet
| Grade | Assay/Purity | Melting/Boiling Point | Moisture/LOD | Residue on Ignition | Related Substances | Solubility |
|---|---|---|---|---|---|---|
| 98% For Synthesis | ≥ 98% | m.p. 10.5 °C; b.p. 277 °C; 144 °C at 4 mm Hg | ≤ 0.5% | Not specified | Not specified | Miscible with ethanol, ethyl ether; soluble in carbon tetrachloride |
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