Allyl chloride

1.1 — Product identifier

Chemical Name

Allyl chloride

Catalogue No.

AL0176

Product form

Substance

CAS Number

107-05-1

EC Number

203-457-6

Grade

98% For Synthesis

EC Index Number

603-007-00-4

Chemical Formula

C3H5Cl

HSN Code

29032900

Synonyms

3-Chloropropene

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Used as an allylating agent in organic synthesis and as an intermediate in the production of epichlorohydrin.

Uses advised against

Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification

Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail

Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Flam. Liq. 2; Acute Tox. 3; Skin Irrit. 2; Eye Dam. 1; STOT SE 3; Muta. 2; Carc. 2; STOT RE 2; Aquatic Acute 1

Classification source

ECHA C&L Inventory via PubChem CID 7850 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms

Flammable, Corrosive, Acute Toxic, Health Hazard

Signal word

Danger

Hazard statements

H225: Highly Flammable liquid and vapor; H301+H311+H331: Toxic if swallowed, in contact with skin or if inhaled; H301: Toxic if swallowed; H311: Toxic in contact with skin; H315: Causes skin irritation; H318: Causes serious eye damage; H331: Toxic if inhaled; H335: May cause respiratory irritation; H341: Suspected of causing genetic defects; H351: Suspected of causing cancer; H373: May causes damage to organs through prolonged or repeated exposure

2.3 — Other hazards

Other hazards

Highly flammable; may cause respiratory irritation.

3.1 — Substance

Name

Allyl chloride

CAS No.

107-05-1

4.1 — Description of first aid measures

First-aid measures after inhalation

If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact

If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.

First-aid measures after eye contact

If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion

If this chemical has been swallowed, get medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use

Irritation of the respiratory tract, skin, and eyes; headache; dizziness; nausea.

4.3 — Indication of any immediate medical attention and special treatment needed

General information

Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media

Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media

Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures

Vapor is heavier than air (vapor-air density at 100 °F, 2.2) and may travel considerable distance to source of ignition and flash back.

5.3 — Advice for firefighters

Protection during firefighting

Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures

Evacuate area. Ventilate. Use appropriate protective equipment. Prevent entry into waterways.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up

Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

6.4 — Reference to other sections

Reference

Not specified

7.1 — Precautions for safe handling

Precautions for safe handling

Use in a fume hood. Wear appropriate personal protective equipment (PPE). Avoid contact with skin and eyes.

Hygiene measures

Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions

Fireproof. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Dry.

8.2 — Exposure controls

Hand protection

Protective gloves (e.g. nitrile rubber)

Eye protection

Chemical safety goggles or safety glasses

Skin and body protection

Wear suitable protective clothing

Respiratory protection

(1 ppm to 2% for 0.5 hr or less) full face mask and canister; (greater concentrations) self-contained breathing apparatus or its equivalent. Rubber or neoprene gloves, apron, boots; clean body-covering clothes; chemical goggles, gas-tight goggles, or equivalent; full face shield.

9.1 — Information on basic physical and chemical properties

Physical state

Liquid

Colour

Colorless to pale yellow

Odour

Pungent, unpleasant odor.

Odour threshold

Not specified

pH value

Not applicable

Relative evaporation rate (butylacetate=1)

Not specified

Melting point

-134.5 °C

Freezing point

Not specified

Boiling point

44-45 °C

Flash point

-32 °C

Auto-ignition temperature

Ignition temp, 737 °F (392 °C)

Decomposition temperature

Not specified

Flammability (solid, gas)

Highly flammable liquid and vapor

Vapour pressure

368 mm Hg at 25 °C

Relative vapour density at 20°C

2.64 (Air= 1)

Density

0.938 at 20 °C/4 °C

Solubility

Miscible with alcohol, chloroform, ether, petrol ether

Log Pow

2.1

Viscosity, kinematic

Not specified

Viscosity, dynamic

Not specified

Explosive properties

Not specified

Oxidising properties

Not specified

Explosive limits

Not specified

10.1 — Reactivity

Reactivity

Reacts with strong oxidizing agents and bases.

10.2 — Chemical stability

Chemical stability

Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions

The substance polymerizes under the influence of acids, heat and peroxides. This generates fire or explosion hazard. On combustion, forms toxic and corrosive fumes of hydrogen chloride (see ICSC 0163).

10.4 — Conditions to avoid

Conditions to avoid

Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials

Strong oxidizers, strong bases, and amines.

10.6 — Hazardous decomposition products

Hazardous decomposition products

Not specified

11.1 — Information on toxicological effects

Acute toxicity

LD50 Rabbit dermal 2066 mg/kg; LD50 Dog iv 7.15 mg/kg; LD50 Mouse ip 155 mg/kg

Skin corrosion/irritation

H315: Causes skin irritation

Serious eye damage/irritation

H318: Causes serious eye damage

Respiratory or skin sensitisation

Not classified (based on available data)

Germ cell mutagenicity

H341: Suspected of causing genetic defects

Carcinogenicity

H351: Suspected of causing cancer

Specific target organ toxicity (single exposure)

H335: May cause respiratory irritation

Specific target organ toxicity (repeated exposure)

H373: May causes damage to organs through prolonged or repeated exposure

12.1 — Toxicity

Toxicity information

Not specified

12.2 — Persistence - degradability

Persistence - degradability

Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential

Not specified

12.4 — Mobility in soil

Mobility in soil

Not specified

12.6 — Other adverse effects

Environmental precautions

Not specified

13.1 — Waste treatment methods

Additional Info

Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)

UN 1100

UN-No. (IMDG)

UN 1100

UN-No. (IATA)

UN 1100

UN-No. (ADN)

UN 1100

UN-No. (RID)

UN 1100

14.2 — UN proper shipping name

Proper Shipping Name (ADR)

Allyl chloride

Proper Shipping Name (IMDG)

Allyl chloride

Proper Shipping Name (IATA)

Allyl chloride

Proper Shipping Name (ADN)

Allyl chloride

Proper Shipping Name (RID)

Allyl chloride

14.3 — Transport hazard class(es)

Transport hazard class(es)

3 (6.1)

14.4 — Packing group

Packing group (ADR)

I

Packing group (IMDG)

I

Packing group (IATA)

I

Packing group (ADN)

I

Packing group (RID)

I

14.5 — Environmental hazards

Dangerous for the environment

Not specified

Marine pollutant

Not specified

Other information

No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations

Not specified