Aniline

1.1 — Product identifier

Chemical Name

Aniline

Catalogue No.

AL0433

Product form

Substance

CAS Number

62-53-3

EC Number

200-539-3

Grade

99% For Synthesis

EC Index Number

612-005-00-5

Chemical Formula

C6H5NH2

HSN Code

29214110

Synonyms

Phenylamine, Aminobenzene

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Intermediate in the synthesis of dyes, pharmaceuticals, and other chemicals.

Uses advised against

Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification

Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail

Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Acute Tox. 3; Skin Sens. 1; Eye Dam. 1; Muta. 2; Carc. 2; STOT RE 1; Aquatic Acute 1

Classification source

ECHA C&L Inventory via PubChem CID 6115 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms

Corrosive, Acute Toxic, Health Hazard, Environmental Hazard

Signal word

Danger

Hazard statements

H301: Toxic if swallowed; H311: Toxic in contact with skin; H317: May cause an allergic skin reaction; H318: Causes serious eye damage; H331: Toxic if inhaled; H341: Suspected of causing genetic defects; H351: Suspected of causing cancer; H372: Causes damage to organs through prolonged or repeated exposure; H400: Very toxic to aquatic life

2.3 — Other hazards

Other hazards

May cause respiratory irritation; harmful to aquatic life with long lasting effects.

3.1 — Substance

Name

Aniline

CAS No.

62-53-3

4.1 — Description of first aid measures

First-aid measures after inhalation

If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact

If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.

First-aid measures after eye contact

If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion

If this chemical has been swallowed, get medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use

Headache, dizziness, nausea, skin irritation, respiratory distress.

4.3 — Indication of any immediate medical attention and special treatment needed

General information

Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media

Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures

Vapors are heavier than air and will collect in low areas. Vapors may travel long distances to ignition sources and flashback.

5.3 — Advice for firefighters

Protection during firefighting

Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures

Evacuate area. Ventilate. Contain spill and absorb with inert material.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up

Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent.

6.4 — Reference to other sections

Reference

Not specified

7.1 — Precautions for safe handling

Precautions for safe handling

Use in a fume hood. Wear appropriate personal protective equipment (PPE).

Hygiene measures

Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions

Separated from strong oxidants, strong acids and food and feedstuffs. Well closed. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.

8.2 — Exposure controls

Hand protection

Handle with gloves.

Eye protection

Tightly fitting safety goggles. Faceshield (8-inch minimum).

Skin and body protection

Wear suitable protective clothing

Respiratory protection

Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state

Liquid

Colour

Colorless to pale yellow

Odour

Hedonic tone; pungent

Odour threshold

Not available

pH value

Not applicable

Relative evaporation rate (butylacetate=1)

Not available

Melting point

-6.0 °C

Freezing point

-6 °C

Boiling point

184.1 °C

Flash point

70 °C (158 °F) - closed cup

Auto-ignition temperature

1139 °F (615 °C)

Decomposition temperature

Not available

Flammability (solid, gas)

Not applicable

Vapour pressure

6.67X10-1 mm Hg at 25 °C

Relative vapour density at 20°C

3.3 (Air = 1)

Density

1.0217 at 20 °C/20 °C

Solubility

In water, 36,000 mg/L at 25 °C

Log Pow

0.90

Viscosity, kinematic

Not available

Viscosity, dynamic

0.89 mPa·s at 20 °C

Explosive properties

Not explosive

Oxidising properties

Not oxidizing

Explosive limits

1.2 - 7.0 vol% in air

10.1 — Reactivity

Reactivity

Stable under normal conditions. Reacts with strong oxidizing agents.

10.2 — Chemical stability

Chemical stability

Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions

Decomposes above 190 °C . This produces toxic and corrosive fumes of nitrogen oxides and ammonia and flammable vapours. Reacts with strong acids and strong oxidants. This generates fire and explosion hazard.

10.4 — Conditions to avoid

Conditions to avoid

Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials

Strong oxidizers, strong acids, and bases.

10.6 — Hazardous decomposition products

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions - Carbon oxides, nitrogen oxides (NOx).

11.1 — Information on toxicological effects

Acute toxicity

LD50 Rat oral 250 mg/kg; LD50 Rat dermal 1400 mg/kg; LD50 Rat ip 420 mg/kg

Skin corrosion/irritation

Not classified (based on available data)

Serious eye damage/irritation

H318: Causes serious eye damage

Respiratory or skin sensitisation

H317: May cause an allergic skin reaction

Germ cell mutagenicity

H341: Suspected of causing genetic defects

Carcinogenicity

H351: Suspected of causing cancer

Specific target organ toxicity (single exposure)

Not classified (based on available data)

Specific target organ toxicity (repeated exposure)

H372: Causes damage to organs through prolonged or repeated exposure

12.1 — Toxicity

Toxicity information

Not specified

12.2 — Persistence - degradability

Persistence - degradability

Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential

Not specified

12.4 — Mobility in soil

Mobility in soil

Not specified

12.6 — Other adverse effects

Environmental precautions

Not specified

13.1 — Waste treatment methods

Additional Info

Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)

UN 1547

UN-No. (IMDG)

UN 1547

UN-No. (IATA)

UN 1547

UN-No. (ADN)

UN 1547

UN-No. (RID)

UN 1547

14.2 — UN proper shipping name

Proper Shipping Name (ADR)

Aniline

Proper Shipping Name (IMDG)

Aniline

Proper Shipping Name (IATA)

Aniline

Proper Shipping Name (ADN)

Aniline

Proper Shipping Name (RID)

Aniline

14.3 — Transport hazard class(es)

Transport hazard class(es)

6.1

14.4 — Packing group

Packing group (ADR)

II

Packing group (IMDG)

II

Packing group (IATA)

II

Packing group (ADN)

II

Packing group (RID)

II

14.5 — Environmental hazards

Dangerous for the environment

Not specified

Marine pollutant

Not specified

Other information

No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations

Not specified