Benzoyl Peroxide

1.1 — Product identifier

Chemical Name

Benzoyl Peroxide

Catalogue No.

AL0640

Product form

Substance

CAS Number

94-36-0

EC Number

202-327-6

Grade

75%

EC Index Number

617-008-00-0

Chemical Formula

C14H10O4

HSN Code

29163200

Synonyms

Benzoyl peroxide, Peroxybenzoic acid

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Radical initiator, acne treatment

Uses advised against

Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification

Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail

Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Org. Perox. B; Skin Sens. 1; Eye Irrit. 2; Aquatic Acute 1

Classification source

ECHA C&L Inventory via PubChem CID 7187 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms

Explosive, Flammable, Irritant, Environmental Hazard

Signal word

Danger

Hazard statements

H241: Heating may cause a fire or explosion; H317: May cause an allergic skin reaction; H319: Causes serious eye irritation; H400: Very toxic to aquatic life

2.3 — Other hazards

Other hazards

Organic peroxide; may cause skin and eye irritation.

3.1 — Substance

Name

Benzoyl Peroxide

CAS No.

94-36-0

4.1 — Description of first aid measures

First-aid measures after inhalation

If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact

If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.

First-aid measures after eye contact

If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion

If this chemical has been swallowed, get medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use

Irritation of skin, eyes, and respiratory tract.

4.3 — Indication of any immediate medical attention and special treatment needed

General information

Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media

Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures

Vapors are heavier than air and will collect in low areas. Vapors may travel long distances to ignition sources and flashback.

5.3 — Advice for firefighters

Protection during firefighting

Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures

Evacuate area. Avoid dust formation. Use appropriate protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up

Evacuate danger area! Remove all ignition sources. Wash away remainder with plenty of water. Do NOT absorb in saw-dust or other combustible absorbents.

6.4 — Reference to other sections

Reference

Not specified

7.1 — Precautions for safe handling

Precautions for safe handling

Avoid contact with skin and eyes. Use personal protective equipment as required.

Hygiene measures

Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions

Fireproof. Separated from combustible substances and reducing agents. Store only in original packaging. See Chemical Dangers.

8.2 — Exposure controls

Hand protection

Handle with gloves.

Eye protection

Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection

Wear suitable protective clothing

Respiratory protection

Use in a well-ventilated area. If exposure limits are exceeded, use appropriate respiratory protection.

9.1 — Information on basic physical and chemical properties

Physical state

Solid

Colour

White

Odour

Faint, benzaldehyde-like odor.

Odour threshold

Not determined

pH value

Not applicable

Relative evaporation rate (butylacetate=1)

Not applicable

Melting point

104.5 °C

Freezing point

Not applicable

Boiling point

Not applicable

Flash point

80 °C

Auto-ignition temperature

80 °C

Decomposition temperature

> 100 °C

Flammability (solid, gas)

Not flammable under normal conditions

Vapour pressure

VP: < 0.1 torr at 20 °C

Relative vapour density at 20°C

Not applicable

Density

1.3340 at 25 °C

Solubility

In water, 9.10 mg/L at 25 °C

Log Pow

3.46

Viscosity, kinematic

Not applicable

Viscosity, dynamic

Not applicable

Explosive properties

Not explosive under normal conditions

Oxidising properties

Strong oxidizer

Explosive limits

Not applicable

10.1 — Reactivity

Reactivity

Stable under recommended storage conditions; may decompose upon heating.

10.2 — Chemical stability

Chemical stability

Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions

May decompose explosively on shock, friction or concussion. May explode on heating above 103-105 °C. On combustion, forms irritating and toxic fumes and gases of benzoic acid (see ICSC 0103) and carbon monoxide (see ICSC 0023). The substance is a strong oxidant.

10.4 — Conditions to avoid

Conditions to avoid

Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials

Reducing agents, strong acids, strong bases, and heat sources.

10.6 — Hazardous decomposition products

Hazardous decomposition products

Explosive decomposition above the melting point (103 °C) forms flammable products.

11.1 — Information on toxicological effects

Acute toxicity

LD50 Rat oral 7710 mg/kg; LD50 Mouse oral 5700 mg/kg; LD50 Mouse ip 206-242 mg/kg body weight

Skin corrosion/irritation

Not classified (based on available data)

Serious eye damage/irritation

H319: Causes serious eye irritation

Respiratory or skin sensitisation

H317: May cause an allergic skin reaction

Germ cell mutagenicity

Not classified (based on available data)

Carcinogenicity

Not classified (based on available data)

Specific target organ toxicity (single exposure)

Not classified (based on available data)

Specific target organ toxicity (repeated exposure)

Not classified (based on available data)

12.1 — Toxicity

Toxicity information

Not specified

12.2 — Persistence - degradability

Persistence - degradability

Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential

Not specified

12.4 — Mobility in soil

Mobility in soil

Not specified

12.6 — Other adverse effects

Environmental precautions

Not specified

13.1 — Waste treatment methods

Additional Info

Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)

3104

UN-No. (IMDG)

3104

UN-No. (IATA)

3104

UN-No. (ADN)

3104

UN-No. (RID)

3104

14.2 — UN proper shipping name

Proper Shipping Name (ADR)

Benzoyl peroxide, moist

Proper Shipping Name (IMDG)

Benzoyl peroxide, moist

Proper Shipping Name (IATA)

Benzoyl peroxide, moist

Proper Shipping Name (ADN)

Benzoyl peroxide, moist

Proper Shipping Name (RID)

Benzoyl peroxide, moist

14.3 — Transport hazard class(es)

Transport hazard class(es)

5.2

14.4 — Packing group

Packing group (ADR)

II

Packing group (IMDG)

II

Packing group (IATA)

II

Packing group (ADN)

II

Packing group (RID)

II

14.5 — Environmental hazards

Dangerous for the environment

Not specified

Marine pollutant

Not specified

Other information

No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations

Not specified