Chloroform

99% For Synthesis For Laboratory Use
CAS Number
67-66-3
HSN Code
29031300
Molecular Formula
CHCl3
Catalogue Number
AL1296
Purity
≥99%
Molecular Weight
119.38 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Highly refractive, nonflammable, heavy, very volatile liquid
Shelf Life 2 years
Packaging Available in: 250 ml glass bottle with tin cap, 500 ml glass bottle with tin cap, 1 Lt glass bottle with tin cap, 2.5 Lt glass bottle with tin cap, 5 Lt plastic container, 25 Lt plastic drum
Storage Store only in original container. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Ventilation along the floor. Store in an area without drain or sewer access.

Chloroform appears as a clear colorless liquid with a characteristic odor. Denser (12.3 lb / gal) than water and slightly soluble in water.

Also known as Trichloromethane.

Catalogue No.
AL1296
CAS Number
67-66-3
Molecular Formula
CHCl3
Molecular Weight
119.38 g/mol
HSN Code
29031300
Grade
99% For Synthesis
Product Form
Substance

Melting point: -63.47 °C; Boiling point: 61.12 °C; Density: 1.4788 g/cu cm at 25 °C; Solubility: In water, 7.95X10+3 mg/L at 25 °C.

Appearance
Highly refractive, nonflammable, heavy, very volatile liquid
Shelf Life
2 years
Packaging
Available in: 250 ml glass bottle with tin cap, 500 ml glass bottle with tin cap, 1 Lt glass bottle with tin cap, 2.5 Lt glass bottle with tin cap, 5 Lt plastic container, 25 Lt plastic drum
Storage
Store only in original container. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Ventilation along the floor. Store in an area without drain or sewer access.

1.1 — Product identifier

Chemical Name
Chloroform
Catalogue No.
AL1296
Product form
Substance
CAS Number
67-66-3
EC Number
200-663-8
Grade
99% For Synthesis
EC Index Number
602-006-00-4
Chemical Formula
CHCl3
HSN Code
29031300
Synonyms
Trichloromethane

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Solvent in organic synthesis and extraction processes.
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4; Skin Irrit. 2; Eye Irrit. 2; Acute Tox. 3; Carc. 2; Repr. 2; STOT RE 1; STOT RE 2
Classification source
ECHA C&L Inventory via PubChem CID 6212 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Acute Toxic, Health Hazard
Signal word
Danger
Hazard statements
H302: Harmful if swallowed; H315: Causes skin irritation; H319: Causes serious eye irritation; H331: Toxic if inhaled; H351: Suspected of causing cancer; H361: Suspected of damaging fertility or the unborn child; H372: Causes damage to organs through prolonged or repeated exposure; H373: May causes damage to organs through prolonged or repeated exposure

2.3 — Other hazards

Other hazards
Suspected carcinogen; may cause reproductive toxicity.

3.1 — Substance

Name
Chloroform
CAS No.
67-66-3

4.1 — Description of first aid measures

First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Headache, dizziness, nausea, vomiting, and potential central nervous system effects.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
The vapour is heavier than air and may accumulate in lowered spaces causing a deficiency of oxygen.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Contain spill and absorb with inert material.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Use in a fume hood. Wear appropriate personal protective equipment (PPE).
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store only in original container. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Ventilation along the floor. Store in an area without drain or sewer access.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless
Odour
Pleasant, etheric, nonirritating
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-63.47 °C
Freezing point
Not specified
Boiling point
61.12 °C
Flash point
No data available
Auto-ignition temperature
Not specified
Decomposition temperature
Not specified
Flammability (solid, gas)
Not applicable
Vapour pressure
VP: 100 mm Hg at 10.4 °C
Relative vapour density at 20°C
4.12 (Air = 1)
Density
1.4788 g/cu cm at 25 °C
Solubility
In water, 7.95X10+3 mg/L at 25 °C
Log Pow
1.97
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified

10.1 — Reactivity

Reactivity
Stable under normal conditions; reacts with strong oxidizing agents.

10.2 — Chemical stability

Chemical stability
Decomposes at ordinary temp in sunlight in the absence of air, and in the dark in the presence of air.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
Decomposes on heating. This produces toxic and corrosive fumes of hydrogen chloride (see ICSC 0163), phosgene (see ICSC 0007) and chlorine (see ICSC 0126). Reacts violently with strong bases, strong oxidants, alkalis, acetone and some metals such as aluminium, magnesium and zinc.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong oxidizers, strong bases, and amines.

10.6 — Hazardous decomposition products

Hazardous decomposition products
When heated to decomposition forms phosgene gas.

11.1 — Information on toxicological effects

Acute toxicity
LD50 Rat oral 2180 mg/kg; LD50 Rabbit oral 9827 mg/kg; LD50 Rat intragastric 2000 mg/kg
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
H319: Causes serious eye irritation
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
H351: Suspected of causing cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
H372: Causes damage to organs through prolonged or repeated exposure; H373: May causes damage to organs through prolonged or repeated exposure

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
1888
UN-No. (IMDG)
1888
UN-No. (IATA)
1888
UN-No. (ADN)
1888
UN-No. (RID)
1888

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Chloroform
Proper Shipping Name (IMDG)
Chloroform
Proper Shipping Name (IATA)
Chloroform
Proper Shipping Name (ADN)
Chloroform
Proper Shipping Name (RID)
Chloroform

14.3 — Transport hazard class(es)

Transport hazard class(es)
6.1

14.4 — Packing group

Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Used as an extraction solvent in organic synthesis and analytical chemistry.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL00454
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
119.38 g/mol
Test Standard Observed
Assay ≥99% 99.5%
Density 1.480-1.492 g/mL 1.485 g/mL
Boiling Point 61.2 °C 61.5 °C
Moisture Content ≤0.1% 0.05%
Residue on Ignition ≤0.01% 0.005%
Related Substances None detected None detected

The above product is expected to comply with 99% For Synthesis grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
99% For Synthesis ≥99% m.p. -63.47 °C; b.p. 61.12 °C ≤0.1% ≤0.01% None detected In water, 7.95X10+3 mg/L at 25 °C
View full Technical Data Sheet

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