Fluoroboric Acid

40% For Synthesis For Laboratory Use
CAS Number
16872-11-0
HSN Code
28111990
Molecular Formula
HBF4
Catalogue Number
AL2199
Purity
40%
Molecular Weight
87.81 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Colorless liquid
Shelf Life -
Packaging Available in: 500 ml glass bottle, 2.5 Lt glass bottle
Storage Separated from strong bases, metals and food and feedstuffs. Well closed. Ventilation along the floor. Store only in original container. Do NOT store or transport in containers made from metal or glass. Store in an area without drain or sewer access.

Tetrafluoroboric acid is a boron fluoride. It is a conjugate acid of a tetrafluoroborate(1-).

Also known as Borofluoric acid.

Catalogue No.
AL2199
CAS Number
16872-11-0
Molecular Formula
HBF4
Molecular Weight
87.81 g/mol
HSN Code
28111990
Grade
40% For Synthesis
Product Form
Substance

Boiling point: 130 °C decomposes; Density: Approximately 1.8 g/cu cm; Solubility: Very soluble in water, ethanol.

Appearance
Colorless liquid
Shelf Life
-
Packaging
Available in: 500 ml glass bottle, 2.5 Lt glass bottle
Storage
Separated from strong bases, metals and food and feedstuffs. Well closed. Ventilation along the floor. Store only in original container. Do NOT store or transport in containers made from metal or glass. Store in an area without drain or sewer access.

1.1 — Product identifier

Chemical Name
Fluoroboric Acid
Catalogue No.
AL2199
Product form
Substance
CAS Number
16872-11-0
EC Number
240-898-3
Grade
40% For Synthesis
EC Index Number
Boric acid, fluoroboric acid
Chemical Formula
HBF4
HSN Code
28111990
Synonyms
Borofluoric acid

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a catalyst and electrolyte in metal plating and organic synthesis.
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Skin Corr. 1B; Eye Dam. 1
Classification source
ECHA C&L Inventory via PubChem CID 28118 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Corrosive
Signal word
Danger
Hazard statements
H314: Causes severe skin burns and eye damage; H318: Causes serious eye damage

2.3 — Other hazards

Other hazards
Corrosive to metals and tissue.

3.1 — Substance

Name
Fluoroboric Acid
CAS No.
16872-11-0

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. Seek medical attention if symptoms persist.
First-aid measures after skin contact
Wash with plenty of soap and water. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Corrosive effects may include burns, irritation, and respiratory distress.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Non-flammable, but may emit toxic fumes in a fire.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Contain spill and neutralize with a suitable alkaline material.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Personal protection: complete protective clothing including self-contained breathing apparatus. Consult an expert! Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Use personal protective equipment. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Separated from strong bases, metals and food and feedstuffs. Well closed. Ventilation along the floor. Store only in original container. Do NOT store or transport in containers made from metal or glass. Store in an area without drain or sewer access.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless to pale yellow
Odour
Odourless
Odour threshold
Not applicable
pH value
<1
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
-30 °C
Freezing point
Not applicable
Boiling point
130 °C decomposes
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not applicable
Flammability (solid, gas)
Not applicable
Vapour pressure
Not specified
Relative vapour density at 20°C
Not specified
Density
Approximately 1.8 g/cu cm
Solubility
Very soluble in water, ethanol
Log Pow
Not specified
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not applicable
Oxidising properties
Not applicable
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Reacts violently with strong bases and may release toxic gases.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
Decomposes on heating. This produces toxic and corrosive fumes including hydrogen fluoride and fluorine compounds. The solution in water is a strong acid.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong bases, metals, and oxidizing agents.

10.6 — Hazardous decomposition products

Hazardous decomposition products
When heated to decomposition it emits toxic vapors of boron and hydrogen fluoride.

11.1 — Information on toxicological effects

Acute toxicity
LD50 Rat oral 100-200 mg/kg bw; LD50 Rat oral 464-1000 mgkg bw 51% Tetrafluoroboric acid/; LD50 Mouse oral <50 mg/kg bw
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
1775
UN-No. (IMDG)
1775
UN-No. (IATA)
1775
UN-No. (ADN)
1775
UN-No. (RID)
1775

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Fluoroboric Acid
Proper Shipping Name (IMDG)
Fluoroboric Acid
Proper Shipping Name (IATA)
Fluoroboric Acid
Proper Shipping Name (ADN)
Fluoroboric Acid
Proper Shipping Name (RID)
Fluoroboric Acid

14.3 — Transport hazard class(es)

Transport hazard class(es)
8

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Fluoroboric acid is utilized as an acid catalyst in organic synthesis and as an electrolyte in metal electroplating processes, particularly for tin and lead.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL0745D
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
87.81 g/mol
Test Standard Observed
Description Clear colorless liquid Clear colorless liquid
Assay (Min.) 40.0% 41.2%
Iron (Fe) <0.005% 0.004%
Copper (Cu) <0.0005% <0.0005%
Nickel (Ni) <0.0005% 0.0004%
Zinc (Zn) <0.0005% 0.0004%
Sulphate (SO4) <0.1% <0.1%
Free boric acid 12% 1.45%
Chloride (Cl) <0.005% <0.005%

The above product complies with LR grade

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
40% For Synthesis 40% b.p. 130 °C decomposes Not specified Not specified Not specified Very soluble in water, ethanol
View full Technical Data Sheet

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