Phenylhydrazine

1.1 — Product identifier

Chemical Name

Phenylhydrazine

Catalogue No.

AL3507

Product form

Substance

CAS Number

100-63-0

EC Number

202-873-5

Grade

97% For Synthesis

EC Index Number

611-059-00-0

Chemical Formula

C6H8N2

HSN Code

29280090

Synonyms

Hydrazine, phenyl-; Phenylhydrazine hydrochloride

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Used in organic synthesis and as a reagent for the identification of carbonyl compounds.

Uses advised against

Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification

Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail

Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Acute Tox. 3; Skin Irrit. 2; Skin Sens. 1; Eye Irrit. 2; Muta. 2; Carc. 1B; STOT RE 1; Aquatic Acute 1

Classification source

ECHA C&L Inventory via PubChem CID 7516 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms

Acute Toxic, Health Hazard, Environmental Hazard

Signal word

Danger

Hazard statements

H301: Toxic if swallowed; H311: Toxic in contact with skin; H315: Causes skin irritation; H317: May cause an allergic skin reaction; H319: Causes serious eye irritation; H331: Toxic if inhaled; H341: Suspected of causing genetic defects; H350: May cause cancer; H372: Causes damage to organs through prolonged or repeated exposure; H400: Very toxic to aquatic life

Precautionary statements

P203, P260, P261, P262, P264, P264+P265, P270, P271, P272, P273, P280, P301+P316, P302+P352, P304+P340, P305+P351+P338, P316, P318, P319, P321, P330, P332+P317, P333+P317, P337+P317, P361+P364, P362+P364, P391, P403+P233, P405, P501

2.3 — Other hazards

Other hazards

Suspected carcinogen; may cause reproductive toxicity.

3.1 — Substance

Name

Phenylhydrazine

CAS No.

100-63-0

4.1 — Description of first aid measures

First-aid measures after inhalation

If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact

If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.

First-aid measures after eye contact

If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion

If this chemical has been swallowed, get medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use

Headache, dizziness, nausea, skin irritation, respiratory distress.

4.3 — Indication of any immediate medical attention and special treatment needed

General information

Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media

Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media

Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures

Toxic fumes may be released in a fire. Use water spray to cool containers.

5.3 — Advice for firefighters

Protection during firefighting

Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures

Evacuate area. Wear appropriate protective equipment. Contain spill and prevent entry into waterways.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up

Evacuate danger area! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. If liquid: collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent.

6.4 — Reference to other sections

Reference

Not specified

7.1 — Precautions for safe handling

Precautions for safe handling

Use only in a fume hood. Wear appropriate personal protective equipment (PPE). Avoid contact with skin and eyes.

Hygiene measures

Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions

Separated from strong oxidants and food and feedstuffs. Store in an area without drain or sewer access.

8.2 — Exposure controls

Hand protection

Protective gloves (e.g. nitrile rubber)

Eye protection

Chemical safety goggles or safety glasses

Skin and body protection

Wear suitable protective clothing

Respiratory protection

Use a NIOSH-approved respirator if exposure limits are exceeded.

9.1 — Information on basic physical and chemical properties

Physical state

Liquid

Colour

Pale yellow to red-brown

Odour

Faint, aromatic odor.

Odour threshold

No data available

pH value

No data available

Relative evaporation rate (butylacetate=1)

No data available

Melting point

19.5 °C

Freezing point

No data available

Boiling point

243.5 °C, decomp (760 mm Hg); 173.5 °C at 100 mm Hg; 148.2 °C at 40 mm Hg;

Flash point

190 °F, 88 °C (closed cup)

Auto-ignition temperature

345 °F (173 °C)

Decomposition temperature

No data available

Flammability (solid, gas)

Flammable liquid

Vapour pressure

0.026 mm Hg at 25 °C

Relative vapour density at 20°C

3.7 (air= 1)

Density

1.0978 at 20 °C/4 °C

Solubility

Sparingly sol petroleum ether, sol in dil acids. Miscible in alcohol, ether, chloroform, and benzene

Log Pow

log Kow= 1.25

Viscosity, kinematic

No data available

Viscosity, dynamic

No data available

Explosive properties

No data available

Oxidising properties

No data available

Explosive limits

No data available

10.1 — Reactivity

Reactivity

Reacts violently with strong oxidizers and acids.

10.2 — Chemical stability

Chemical stability

Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions

Decomposes on burning. This produces toxic fumes including nitrogen oxides. Reacts with strong oxidants.

10.4 — Conditions to avoid

Conditions to avoid

Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials

Strong oxidizing agents, strong acids, and bases.

10.6 — Hazardous decomposition products

Hazardous decomposition products

When heated to decomposition it emits highly toxic fumes of nitrogen oxides.

11.1 — Information on toxicological effects

Acute toxicity

LD50 Rat oral 188 mg/kg; LD50 Mouse oral 175 mg/kg; LD50 Rabbit oral 80 mg/kg

Skin corrosion/irritation

H315: Causes skin irritation

Serious eye damage/irritation

H319: Causes serious eye irritation

Respiratory or skin sensitisation

H317: May cause an allergic skin reaction

Germ cell mutagenicity

H341: Suspected of causing genetic defects

Carcinogenicity

H350: May cause cancer

Specific target organ toxicity (single exposure)

Not classified (based on available data)

Specific target organ toxicity (repeated exposure)

H372: Causes damage to organs through prolonged or repeated exposure

12.1 — Toxicity

Toxicity information

Not specified

12.2 — Persistence - degradability

Persistence - degradability

Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential

Not specified

12.4 — Mobility in soil

Mobility in soil

Not specified

12.6 — Other adverse effects

Environmental precautions

Not specified

13.1 — Waste treatment methods

Additional Info

Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)

UN 2572

UN-No. (IMDG)

UN 2572

UN-No. (IATA)

UN 2572

UN-No. (ADN)

UN 2572

UN-No. (RID)

UN 2572

14.2 — UN proper shipping name

Proper Shipping Name (ADR)

Phenylhydrazine

Proper Shipping Name (IMDG)

Phenylhydrazine

Proper Shipping Name (IATA)

Phenylhydrazine

Proper Shipping Name (ADN)

Phenylhydrazine

Proper Shipping Name (RID)

Phenylhydrazine

14.3 — Transport hazard class(es)

Transport hazard class(es)

6.1

14.4 — Packing group

Packing group (ADR)

II

Packing group (IMDG)

II

Packing group (IATA)

II

Packing group (ADN)

II

Packing group (RID)

II

14.5 — Environmental hazards

Dangerous for the environment

Not specified

Marine pollutant

Not specified

Other information

No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations

Not specified