Sodium Arsenate Heptahydrate

AR (Analytical Reagent) For Laboratory Use
CAS Number
10048-95-0
HSN Code
28429010
Molecular Formula
Na2HAsO4·7H2O
Catalogue Number
AL4064
Purity
98%
Molecular Weight
312.01 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Colorless, monoclinic crystals
Shelf Life 2 years
Packaging Available in: 100 gm glass bottle, 250 gm glass bottle, 500 gm glass bottle
Storage Store in an area without drain or sewer access. Well closed. Separated from acids and food and feedstuffs.

Sodium arsenate heptahydrate (AR, di-sodium hydrogen arsenate) is a soluble arsenic(V) salt that serves as a critical reference compound in analytical chemistry. This compound is notable for its high purity of 98%, making it suitable for various laboratory applications, particularly in the analysis of arsenic content in different matrices. Its molecular weight of 312.01 g/mol and specific CAS number 10048-95-0 further identify its unique chemical identity. Due to its properties, sodium arsenate heptahydrate is essential in research settings where precise arsenic quantification is required.

Also known as Di-sodium hydrogen arsenate heptahydrate.

Catalogue No.
AL4064
CAS Number
10048-95-0
Molecular Formula
Na2HAsO4·7H2O
Molecular Weight
312.01 g/mol
HSN Code
28429010
Grade
AR (Analytical Reagent)
Product Form
Substance

Melting point: 57 °C when rapidly heated; Boiling point: 180 °C at 760 mmHg (decomposes); Density: 1.87; Solubility: 5.46 g100 cc water @ 0 °C; 100 g100 cc water @ 100 °C; sol in glycerol.

Appearance
Colorless, monoclinic crystals
Shelf Life
2 years
Packaging
Available in: 100 gm glass bottle, 250 gm glass bottle, 500 gm glass bottle
Storage
Store in an area without drain or sewer access. Well closed. Separated from acids and food and feedstuffs.

1.1 — Product identifier

Chemical Name
Sodium Arsenate Heptahydrate
Catalogue No.
AL4064
Product form
Substance
CAS Number
10048-95-0
Grade
AR
EC Index Number
Arsenic compounds
Chemical Formula
Na2HAsO4·7H2O
HSN Code
28429010
Synonyms
Di-sodium hydrogen arsenate heptahydrate

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Reference compound in analytical chemistry
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Acute Tox. 3; Carc. 1A; Aquatic Acute 1; Aquatic Chronic 1
Classification source
ECHA C&L Inventory via PubChem CID 61460 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Acute Toxic, Health Hazard, Environmental Hazard
Signal word
Danger
Hazard statements
H301: Toxic if swallowed; H331: Toxic if inhaled; H350: May cause cancer; H400: Very toxic to aquatic life; H410: Very toxic to aquatic life with long lasting effects
Precautionary statements
P203, P261, P264, P270, P271, P273, P280, P301+P316, P304+P340, P316, P318, P321, P330, P391, P403+P233, P405, P501

2.3 — Other hazards

Other hazards
Known human carcinogen; highly toxic.

3.1 — Substance

Name
Sodium Arsenate Heptahydrate
CAS No.
10048-95-0

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. Seek medical attention if symptoms persist.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Symptoms of exposure may include nausea, vomiting, abdominal pain, and neurological effects.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Non-flammable, but may emit toxic fumes in a fire.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment. Contain spill and prevent entry into waterways.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle with care, using appropriate personal protective equipment (PPE) including gloves and goggles. Avoid inhalation and skin contact.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in an area without drain or sewer access. Well closed. Separated from acids and food and feedstuffs.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if airborne concentrations exceed recommended limits.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White to colorless
Odour
Odorless
Odour threshold
Not applicable
pH value
7.0 (1% solution)
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
57 °C when rapidly heated
Freezing point
Not applicable
Boiling point
180 °C at 760 mmHg (decomposes)
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Decomposes above 60 °C
Flammability (solid, gas)
Not flammable
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.87
Solubility
5.46 g100 cc water @ 0 °C; 100 g100 cc water @ 100 °C; sol in glycerol
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions, but decomposes upon heating.

10.2 — Chemical stability

Chemical stability
Effloresces in warm air.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
Decomposes on heating. This produces toxic fumes. Reacts with acids.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong bases, and reducing agents.

10.6 — Hazardous decomposition products

Hazardous decomposition products
When heated to decomp it emits toxic fumes of arsenic.

11.1 — Information on toxicological effects

Acute toxicity
Highly toxic; LD50 (oral, rat) is 14 mg/kg.
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
H350: May cause cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 1685
UN-No. (IMDG)
UN 1685
UN-No. (IATA)
UN 1685
UN-No. (ADN)
UN 1685
UN-No. (RID)
UN 1685

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium arsenate, heptahydrate
Proper Shipping Name (IMDG)
Sodium arsenate, heptahydrate
Proper Shipping Name (IATA)
Sodium arsenate, heptahydrate
Proper Shipping Name (ADN)
Sodium arsenate, heptahydrate
Proper Shipping Name (RID)
Sodium arsenate, heptahydrate

14.3 — Transport hazard class(es)

Transport hazard class(es)
6.1

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium arsenate heptahydrate is primarily used as a reference compound in arsenic analytical chemistry, particularly in the calibration of instruments and methods for arsenic detection. It is also utilized in various research applications, including toxicology studies and environmental monitoring, where arsenic levels need to be accurately measured. Additionally, this compound finds use in the preparation of arsenic-containing reagents and in the study of arsenic's biochemical effects. Industries such as pharmaceuticals, environmental science, and analytical laboratories frequently employ this compound in their operations.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01348
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
312.01 g/mol
Test Standard Observed
Description White crystalline powder White crystalline powder
Assay 98.0 - 102.0% 99.14%
Insoluble matter <0.005% <0.005%
Arsenite (As2O3) <0.01% <0.01%
Chloride (Cl) <0.001% 0.0008%
Nitrate (NO3) <0.005% 0.004%
Sulphates (SO4) <0.01% 0.009%
Heavy metals (as Pb) <0.002% 0.001%
Iron (Fe) <0.001% <0.001%

The above product complies with AR grade

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
AR 98% m.p. 57 °C when rapidly heated; b.p. 180 °C at 760 mmHg (decomposes) < 1% < 0.5% None detected 5.46 g100 cc water @ 0 °C; 100 g100 cc water @ 100 °C; sol in glycerol
View full Technical Data Sheet

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