Sodium Azide
- CAS Number
- 26628-22-8
- HSN Code
- 28500030
- Molecular Formula
- NaN3
- Catalogue Number
- AL4072
- Purity
- 99%
- Molecular Weight
- 65.01 g/mol
Complies with : IP | BP | USP | EP | ACS
ISO 9001
ISO 14001
GMP
COA with every batch
Key Properties
Sodium azide is the sodium salt of hydrogen azide (hydrazoic acid). It has a role as a mitochondrial respiratory-chain inhibitor, a mutagen, an antibacterial agent and an explosive.
Also known as Sodium azide, Azide of sodium.
- Catalogue No.
- AL4072
- CAS Number
- 26628-22-8
- Molecular Formula
- NaN3
- Molecular Weight
- 65.01 g/mol
- HSN Code
- 28500030
- Grade
- AR 99%
- Product Form
- Substance
Melting point: 275 °C (decomp); Density: 1.846 at 20 °C; Solubility: In water, 41.0 g/100 mL at 17 °C.
- Appearance
- Colorless hexagonal crystals
- Shelf Life
- Stable under recommended storage conditions
- Packaging
- Available in: 100 gm glass bottle, 500 gm glass bottle
- Storage
- Separated from food and feedstuffs, acids and metals. See Chemical Dangers. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.
1.1 — Product identifier
- Chemical Name
- Sodium Azide
- Catalogue No.
- AL4072
- Product form
- Substance
- CAS Number
- 26628-22-8
- EC Number
- 247-852-1
- Grade
- AR 99%
- EC Index Number
- 011-004-00-7
- Chemical Formula
- NaN3
- HSN Code
- 28500030
- Synonyms
- Sodium azide, Azide of sodium
1.2 — Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture
- Analytical reagent, bacteriostatic preservative
- Uses advised against
- Not specified
1.3 — Details of the supplier of the safety data sheet
- Company identification
- Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 — Emergency Contact Details
- Phone / e-Mail
- Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
2.1 — Classification of the substance or mixture
- Classification according to Regulation (EC) No 1272/2008
- Acute Tox. 2; Aquatic Acute 1; Aquatic Chronic 1
- Classification source
- ECHA C&L Inventory via PubChem CID 33557 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 — Label elements
- Hazard pictograms
- Acute Toxic, Environmental Hazard
- Signal word
- Danger
- Hazard statements
- H300: Fatal if swallowed; H400: Very toxic to aquatic life; H410: Very toxic to aquatic life with long lasting effects
2.3 — Other hazards
- Other hazards
- Highly toxic, potential explosive reactions with heavy metals
3.1 — Substance
- Name
- Sodium Azide
- CAS No.
- 26628-22-8
4.1 — Description of first aid measures
- First-aid measures after inhalation
- If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
- First-aid measures after skin contact
- If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.
- First-aid measures after eye contact
- If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
- First-aid measures after ingestion
- If this chemical has been swallowed, get medical attention immediately.
4.2 — Most important symptoms and effects, both acute and delayed
- Symptoms relating to use
- Symptoms of exposure may include headache, dizziness, nausea, vomiting, and respiratory distress.
4.3 — Indication of any immediate medical attention and special treatment needed
- General information
- Treat symptomatically. Show this safety data sheet to the treating physician.
5.1 — Extinguishing media
- Suitable extinguishing media
- Dry powder.
- Unsuitable extinguishing media
- Not specified
5.2 — Special hazards arising from the substance or mixture
- Special procedures
- - Sodium azide will initially sink in water. ; - Sodium azide is decomposed by sunlight and irradiation.
5.3 — Advice for firefighters
- Protection during firefighting
- Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1 — For non-emergency personnel
- Emergency procedures
- Evacuate area. Wear appropriate protective equipment. Contain and clean up spills using inert material.
6.3 — Methods and material for containment and cleaning up
- Methods for cleaning up
- Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered plastic containers. If appropriate, moisten first to prevent dusting.
6.4 — Reference to other sections
- Reference
- Not specified
7.1 — Precautions for safe handling
- Precautions for safe handling
- Handle under inert gas. Use appropriate personal protective equipment (PPE) including gloves and goggles.
- Hygiene measures
- Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 — Conditions for safe storage, including any incompatibilities
- Storage conditions
- Separated from food and feedstuffs, acids and metals. See Chemical Dangers. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.
8.2 — Exposure controls
- Hand protection
- Handle with gloves.
- Eye protection
- Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
- Skin and body protection
- Wear suitable protective clothing
- Respiratory protection
- Use a NIOSH-approved respirator if exposure limits are exceeded.
9.1 — Information on basic physical and chemical properties
- Physical state
- Solid
- Colour
- White
- Odour
- Odorless (with traces of water fishy smelling because of HN3 formation)
- Odour threshold
- Not applicable
- pH value
- Not applicable
- Relative evaporation rate (butylacetate=1)
- Not applicable
- Melting point
- 275 °C (decomp)
- Freezing point
- Not applicable
- Boiling point
- 100 °C (decomposes)
- Flash point
- Not applicable
- Auto-ignition temperature
- Not applicable
- Decomposition temperature
- 300 °C
- Flammability (solid, gas)
- Not flammable under normal conditions
- Vapour pressure
- 1 Pa at 20 °C
- Relative vapour density at 20°C
- Not applicable
- Density
- 1.846 at 20 °C
- Solubility
- In water, 41.0 g/100 mL at 17 °C
- Log Pow
- Not applicable
- Viscosity, kinematic
- Not applicable
- Viscosity, dynamic
- Not applicable
- Explosive properties
- Can be explosive when in contact with heavy metals
- Oxidising properties
- Not an oxidizer
- Explosive limits
- Not applicable
10.1 — Reactivity
- Reactivity
- Stable under normal conditions but can react violently with heavy metals and strong acids.
10.2 — Chemical stability
- Chemical stability
- Stable under recommended storage conditions.
10.3 — Possibility of hazardous reactions
- Possibility of hazardous reactions
- Decomposes on heating above 275 °C . This produces toxic fumes. This generates fire and explosion hazard. Reacts with copper, lead, silver, mercury and carbon disulfide.
10.4 — Conditions to avoid
- Conditions to avoid
- Avoid contact with incompatible materials and excessive heat.
10.5 — Incompatible materials
- Incompatible materials
- Heavy metals, strong acids, and oxidizing agents.
10.6 — Hazardous decomposition products
- Hazardous decomposition products
- Hazardous decomposition products formed under fire conditions - Sodium oxides.
11.1 — Information on toxicological effects
- Acute toxicity
- LD50 Rat oral 45 mg/kg; LD50 Mouse sc 23 mg/kg; LD50 Rat sc 45 mg/kg
- Skin corrosion/irritation
- Not classified (based on available data)
- Serious eye damage/irritation
- Not classified (based on available data)
- Respiratory or skin sensitisation
- Not classified (based on available data)
- Germ cell mutagenicity
- Not classified (based on available data)
- Carcinogenicity
- Not classified (based on available data)
- Specific target organ toxicity (single exposure)
- Not classified (based on available data)
- Specific target organ toxicity (repeated exposure)
- Not classified (based on available data)
12.1 — Toxicity
- Toxicity information
- Not specified
12.2 — Persistence - degradability
- Persistence - degradability
- Not specified
12.3 — Bioaccumulative potential
- Bioaccumulative potential
- Not specified
12.4 — Mobility in soil
- Mobility in soil
- Not specified
12.6 — Other adverse effects
- Environmental precautions
- Not specified
13.1 — Waste treatment methods
- Additional Info
- Dispose of contents/container in accordance with local, regional, national and international regulations.
14.1 — UN number
- UN-No. (ADR)
- UN 1687
- UN-No. (IMDG)
- UN 1687
- UN-No. (IATA)
- UN 1687
- UN-No. (ADN)
- UN 1687
- UN-No. (RID)
- UN 1687
14.2 — UN proper shipping name
- Proper Shipping Name (ADR)
- Sodium azide
- Proper Shipping Name (IMDG)
- Sodium azide
- Proper Shipping Name (IATA)
- Sodium azide
- Proper Shipping Name (ADN)
- Sodium azide
- Proper Shipping Name (RID)
- Sodium azide
14.3 — Transport hazard class(es)
- Transport hazard class(es)
- 6.1
14.4 — Packing group
- Packing group (ADR)
- II
- Packing group (IMDG)
- II
- Packing group (IATA)
- II
- Packing group (ADN)
- II
- Packing group (RID)
- II
14.5 — Environmental hazards
- Dangerous for the environment
- Not specified
- Marine pollutant
- Not specified
- Other information
- No supplementary information available
15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture
- 15.1.1 EU-Regulations
- Not specified
Sodium azide is widely used in laboratory research as an analytical-grade bacteriostatic preservative reagent. It is employed in the preparation of various chemical compounds and as a preservative in biological samples. Additionally, sodium azide is utilized in the synthesis of azides and as a propellant in automotive airbag systems. Its applications extend to the pharmaceutical industry, where it is used in the development of certain medications and as a reagent in organic synthesis.
ISO 9001
ISO 14001
GMP
COA with every batch
- Batch Number
- AL-2026-AL1350A
- Manufacturing Date
- September-2026
- Expiry Date
- September-2031
- Molecular Weight
- 65.01 g/mol
| Test | Standard | Observed |
|---|---|---|
| Assay | 99% min | 99.5% |
| Moisture Content | <1% | 0.5% |
| Residue on Ignition | <0.1% | 0.05% |
| Related Substances | None detected | None detected |
| Solubility | 0.1 g/100 mL in water at 20 °C | 0.1 g/100 mL in water at 20 °C |
The above product is expected to comply with AR 99% grade specification.
Technical Data Sheet
| Grade | Assay/Purity | Melting/Boiling Point | Moisture/LOD | Residue on Ignition | Related Substances | Solubility |
|---|---|---|---|---|---|---|
| AR 99% | 99% | m.p. 275 °C (decomp) | <1% | <0.1% | None detected | In water, 41.0 g/100 mL at 17 °C |
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