Sodium Nitrite

AR grade For Laboratory Use
CAS Number
7632-00-0
HSN Code
28341010
Molecular Formula
NaNO2
Catalogue Number
AL4216
Purity
≥ 98%
Molecular Weight
69.00 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White, orthorhombic crystals
Shelf Life 2 years
Packaging Available in: 500 gm plastic bottle
Storage Separated from combustible substances, reducing agents and acids. Dry. Well closed.

Sodium nitrite is an inorganic sodium salt having nitrite as the counterion. Used as a food preservative and antidote to cyanide poisoning.

Also known as Nitrous acid, sodium salt; Sodium nitrite; Sodium nitrite, AR grade.

Catalogue No.
AL4216
CAS Number
7632-00-0
Molecular Formula
NaNO2
Molecular Weight
69.00 g/mol
HSN Code
28341010
Grade
AR grade
Product Form
Substance

Melting point: 271 °C; Boiling point: Decomposes at 608 °F; Density: 2.17; Solubility: Sol in water; moderately sol in methanol; sparingly soluble in diethyl ether.

Appearance
White, orthorhombic crystals
Shelf Life
2 years
Packaging
Available in: 500 gm plastic bottle
Storage
Separated from combustible substances, reducing agents and acids. Dry. Well closed.

1.1 — Product identifier

Chemical Name
Sodium Nitrite
Catalogue No.
AL4216
Product form
Substance
CAS Number
7632-00-0
EC Number
231-555-9
Grade
AR grade
EC Index Number
007-001-00-1
Chemical Formula
NaNO2
HSN Code
28341010
Synonyms
Nitrous acid, sodium salt; Sodium nitrite; Sodium nitrite, AR grade

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Analytical reagent, food preservative, corrosion inhibitor
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Ox. Liq. 3; Acute Tox. 3; Aquatic Acute 1
Classification source
ECHA C&L Inventory via PubChem CID 23668193 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Oxidizer, Acute Toxic, Environmental Hazard
Signal word
Danger
Hazard statements
H272: May intensify fire; oxidizer; H301: Toxic if swallowed; H400: Very toxic to aquatic life

2.3 — Other hazards

Other hazards
Oxidizer; may cause fire or explosion in contact with combustible materials.

3.1 — Substance

Name
Sodium Nitrite
CAS No.
7632-00-0

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If not breathing, give artificial respiration.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Give patient 2 to 4 glasses of water and induce vomiting.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Symptoms of exposure may include headache, dizziness, nausea, and in severe cases, methemoglobinemia.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Evaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment. Contain and collect spillage using inert material.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle with care, avoid contact with skin and eyes. Use appropriate personal protective equipment (PPE).
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Separated from combustible substances, reducing agents and acids. Dry. Well closed.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a NIOSH-approved respirator if exposure limits are exceeded or if irritation occurs.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White to pale yellow
Odour
Faintly sweet
Odour threshold
No data available
pH value
9.0 (1% solution)
Relative evaporation rate (butylacetate=1)
No data available
Melting point
271 °C
Freezing point
No data available
Boiling point
Decomposes at 608 °F
Flash point
No data available
Auto-ignition temperature
538 °C
Decomposition temperature
No data available
Flammability (solid, gas)
Not flammable, but may enhance combustion of other materials
Vapour pressure
No data available
Relative vapour density at 20°C
No data available
Density
2.17
Solubility
Sol in water; moderately sol in methanol; sparingly soluble in diethyl ether
Log Pow
-3.7
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
Not explosive
Oxidising properties
Oxidizer
Explosive limits
No data available

10.1 — Reactivity

Reactivity
Sodium nitrite is stable under normal conditions but can react with strong acids and reducing agents.

10.2 — Chemical stability

Chemical stability
Very slowly oxidizes to nitrate in air.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
May explode on heating above 530 °C. Decomposes on contact with acids. This produces toxic fumes of nitrogen oxides. The substance is a strong oxidant.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong reducing agents, and combustible materials.

10.6 — Hazardous decomposition products

Hazardous decomposition products
When heated to decomposition it emits toxic fumes of nitrogen oxide and sodium oxide.

11.1 — Information on toxicological effects

Acute toxicity
LD50 Rabbit oral 186 mg/kg; LD50 Mouse oral 175 mg/kg; LD50 Mouse ip 158 mg/kg
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
1500
UN-No. (IMDG)
1500
UN-No. (IATA)
1500
UN-No. (ADN)
1500
UN-No. (RID)
1500

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium nitrite
Proper Shipping Name (IMDG)
Sodium nitrite
Proper Shipping Name (IATA)
Sodium nitrite
Proper Shipping Name (ADN)
Sodium nitrite
Proper Shipping Name (RID)
Sodium nitrite

14.3 — Transport hazard class(es)

Transport hazard class(es)
5.1 (6.1)

14.4 — Packing group

Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium nitrite is widely used in analytical chemistry as a reagent for diazotization reactions, which are essential in the synthesis of azo compounds. It is also employed in the Griess reagent method for the determination of nitrite levels in various samples, including environmental and biological matrices. Beyond its analytical applications, sodium nitrite serves as a food preservative, particularly in cured meats, where it helps to inhibit bacterial growth and maintain color. Additionally, it is utilized in the production of dyes, pharmaceuticals, and as a corrosion inhibitor in industrial applications.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1402A
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
69.00 g/mol
Test Standard Observed
Assay ≥ 98% 98.5%
Moisture Content ≤ 1.0% 0.5%
Residue on Ignition ≤ 0.5% 0.3%
Related Substances ≤ 0.5% 0.2%
Solubility Soluble in water Fully soluble in water at 20 °C

The above product is expected to comply with AR grade grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
98% AR ≥ 98% m.p. 271 °C; b.p. Decomposes at 608 °F ≤ 1.0% ≤ 0.5% No more than 0.5% of related substances Sol in water; moderately sol in methanol; sparingly soluble in diethyl ether
View full Technical Data Sheet

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