alpha-Naphthylamine

AR (Analytical Reagent) For Laboratory Use
CAS Number
134-32-7
HSN Code
29214511
Molecular Formula
C10H9N
Catalogue Number
AL3182
Purity
99% min
Molecular Weight
143.19 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Needles from ethanol (aq) or ether
Shelf Life -
Packaging Available in: 100 gm plastic bottle, 500 gm plastic bottle
Storage Dry. Keep in the dark. Well closed.

1-naphthylamine is a naphthylamine that is naphthalene substituted by an amino group at position 1. It has a role as a human xenobiotic metabolite.

Also known as 1-Naphthylamine, 1-Aminonaphthalene.

Catalogue No.
AL3182
CAS Number
134-32-7
Molecular Formula
C10H9N
Molecular Weight
143.19 g/mol
HSN Code
29214511
Grade
AR (Analytical Reagent)
Product Form
Substance

Melting point: 49.2 °C; Boiling point: 300.7 °C; Flash point: 157 °C, 315 °F, (closed cup); Density: 1.114 g/cu cm; Solubility: Crystal powder; becomes bluish on exposure to air and light. Sol in about 27 parts water; sol in alcohol and ether.

Appearance
Needles from ethanol (aq) or ether
Shelf Life
-
Packaging
Available in: 100 gm plastic bottle, 500 gm plastic bottle
Storage
Dry. Keep in the dark. Well closed.

1.1 — Product identifier

Chemical Name
alpha-Naphthylamine
Catalogue No.
AL3182
Product form
Substance
CAS Number
134-32-7
EC Number
205-138-7
Grade
AR
EC Index Number
612-002-00-7
Chemical Formula
C10H9N
HSN Code
29214511
Synonyms
1-Naphthylamine, 1-Aminonaphthalene

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Intermediate in dye and pharmaceutical synthesis.
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4; Aquatic Chronic 2
Classification source
ECHA C&L Inventory via PubChem CID 8640 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Irritant, Environmental Hazard
Signal word
Warning
Hazard statements
H302: Harmful if swallowed; H411: Toxic to aquatic life with long lasting effects

2.3 — Other hazards

Other hazards
Carcinogenic; handle with extreme care.

3.1 — Substance

Name
alpha-Naphthylamine
CAS No.
134-32-7

4.1 — Description of first aid measures

First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Headache, dizziness, nausea, skin irritation, respiratory distress.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Toxic fumes may be released in a fire. Use water spray to cool containers.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Use personal protective equipment. Avoid contact with skin, eyes, and clothing.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Dry. Keep in the dark. Well closed.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respirator if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White to pale tan
Odour
Ammonia-like odor.
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
49.2 °C
Freezing point
Not specified
Boiling point
300.7 °C
Flash point
157 °C, 315 °F, (closed cup)
Auto-ignition temperature
Auto-ignition temperature: 460 °C
Decomposition temperature
Not specified
Flammability (solid, gas)
Not flammable under normal conditions
Vapour pressure
4.18X10-3 mm Hg @ 25 °C
Relative vapour density at 20°C
4.93 (Air= 1)
Density
1.114 g/cu cm
Solubility
Crystal powder; becomes bluish on exposure to air and light. Sol in about 27 parts water; sol in alcohol and ether
Log Pow
2.25
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified

10.1 — Reactivity

Reactivity
Stable under normal conditions, but may react with strong oxidizing agents.

10.2 — Chemical stability

Chemical stability
Oxidizes in air.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
Decomposes on burning. This produces nitrogen oxides and carbon monoxide. The substance is a weak base.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong oxidizing agents, strong acids.

10.6 — Hazardous decomposition products

Hazardous decomposition products
The substance decomposes on burning producing nitrogen oxides and carbon monoxide.

11.1 — Information on toxicological effects

Acute toxicity
LD50 Rat oral 680 mg/kg bw; LC50 Rat inhalation >0.056 mg/L/4 hr; LD50 Rat (female) dermal 447 mg/kg bw
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
2077
UN-No. (IMDG)
2077
UN-No. (IATA)
2077
UN-No. (ADN)
2077
UN-No. (RID)
2077

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
alpha-Naphthylamine
Proper Shipping Name (IMDG)
alpha-Naphthylamine
Proper Shipping Name (IATA)
alpha-Naphthylamine
Proper Shipping Name (ADN)
alpha-Naphthylamine
Proper Shipping Name (RID)
alpha-Naphthylamine

14.3 — Transport hazard class(es)

Transport hazard class(es)
6.1

14.4 — Packing group

Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Used under strictly controlled research conditions due to carcinogenicity. It serves as an intermediate in the synthesis of dyes and pharmaceuticals.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1054B
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
143.19 g/mol
Test Standard Observed
Purity 99% min 99.5%
Melting Point 62-64 °C 63 °C
Moisture Content 0.5% max 0.3%
Residue on Ignition 0.1% max 0.05%
Related Substances None detected None detected
Solubility Slightly soluble in water Slightly soluble in water, soluble in organic solvents

The above product is expected to comply with AR grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
AR 99% min m.p. 49.2 °C; b.p. 300.7 °C 0.5% max 0.1% max None detected Crystal powder; becomes bluish on exposure to air and light. Sol in about 27 parts water; sol in alcohol and ether
View full Technical Data Sheet

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