Bromine

AR grade For Laboratory Use
CAS Number
7726-95-6
HSN Code
28013020
Molecular Formula
Br2
Catalogue Number
AL0811
Purity
99.5%
Molecular Weight
159.81 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Dark reddish-brown, volatile, mobile diatomic liquid; vaporizes at room temperature
Shelf Life -
Packaging Available in: 5x20 ml glass amber type / amber glass, 5x5x20 ml glass amber type / amber glass
Storage Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. See Chemical Dangers. Cool. Dry. Well closed. Keep in a well-ventilated room. Store only in original container. Store in an area without drain or sewer access.

Dibromine is a diatomic bromine.

Also known as Bromine, dibromine.

Catalogue No.
AL0811
CAS Number
7726-95-6
Molecular Formula
Br2
Molecular Weight
159.81 g/mol
HSN Code
28013020
Grade
AR grade
Product Form
Substance

Melting point: -7.2 °C; Boiling point: 58.8 °C; Density: 3.1023 at 25 °C/4 °C; Solubility: Solubility in water (25 °C): 0.2141 molL with formation of 0.00115 molL of HOBr.

Appearance
Dark reddish-brown, volatile, mobile diatomic liquid; vaporizes at room temperature
Shelf Life
-
Packaging
Available in: 5x20 ml glass amber type / amber glass, 5x5x20 ml glass amber type / amber glass
Storage
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. See Chemical Dangers. Cool. Dry. Well closed. Keep in a well-ventilated room. Store only in original container. Store in an area without drain or sewer access.

1.1 — Product identifier

Chemical Name
Bromine
Catalogue No.
AL0811
Product form
Substance
CAS Number
7726-95-6
EC Number
231-778-1
Grade
AR grade
EC Index Number
Br2
Chemical Formula
Br2
HSN Code
28013020
Synonyms
Bromine, dibromine

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Analytical reagent, organic synthesis
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.1 — Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Skin Corr. 1A; Acute Tox. 2; Aquatic Acute 1
Classification source
ECHA C&L Inventory via PubChem CID 24408 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 — Label elements

Hazard pictograms
Corrosive, Acute Toxic, Environmental Hazard
Signal word
Danger
Hazard statements
H314: Causes severe skin burns and eye damage; H330: Fatal if inhaled; H400: Very toxic to aquatic life

2.3 — Other hazards

Other hazards
Corrosive to metals, may cause severe burns.

3.1 — Substance

Name
Bromine
CAS No.
7726-95-6

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention.
First-aid measures after skin contact
Remove contaminated clothing. Rinse skin with plenty of water for at least 15 minutes. Seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth. Seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Burning sensation, coughing, shortness of breath, redness, and pain in skin or eyes.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Special hazards arising from the substance or mixture: Hydrogen bromide gas. Container explosion may occur under fire conditions.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area. Ventilate. Use appropriate protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Evacuate danger area! Consult an expert! Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus. Ventilation. Do NOT let this chemical enter the environment. Remove vapour with fine water spray.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Use only in a fume hood. Wear appropriate PPE including gloves and goggles.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. See Chemical Dangers. Cool. Dry. Well closed. Keep in a well-ventilated room. Store only in original container. Store in an area without drain or sewer access.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a NIOSH-approved respirator if exposure limits are exceeded.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Dark reddish-brown
Odour
Suffocating odor
Odour threshold
No data available
pH value
No data available
Relative evaporation rate (butylacetate=1)
No data available
Melting point
-7.2 °C
Freezing point
No data available
Boiling point
58.8 °C
Flash point
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Flammability (solid, gas)
No data available
Vapour pressure
212 mm Hg at 25 °C
Relative vapour density at 20°C
7.139 g/L at 0 °C, 101.3 kPa
Density
3.1023 at 25 °C/4 °C
Solubility
Solubility in water (25 °C): 0.2141 molL with formation of 0.00115 molL of HOBr
Log Pow
No data available
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
No data available
Oxidising properties
Strong oxidizer
Explosive limits
No data available

10.1 — Reactivity

Reactivity
Reacts violently with reducing agents, organic materials, and alkalis.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
Upon heating, toxic fumes are formed. The substance is a strong oxidant. It reacts violently with combustible and reducing materials.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong bases, reducing agents, metals, and organic compounds.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
LD50 Rat oral 2600 mg/kg bw; LD50 Mouse oral 3100 mg/kg bw; LD50 Rat ip 85.2 ppm
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 1744
UN-No. (IMDG)
UN 1744
UN-No. (IATA)
UN 1744
UN-No. (ADN)
UN 1744
UN-No. (RID)
UN 1744

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Bromine
Proper Shipping Name (IMDG)
Bromine
Proper Shipping Name (IATA)
Bromine
Proper Shipping Name (ADN)
Bromine
Proper Shipping Name (RID)
Bromine

14.3 — Transport hazard class(es)

Transport hazard class(es)
8 (6.1)

14.4 — Packing group

Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Used in analytical bromometric titrations and higher-precision organic synthesis.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL0310A
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
159.81 g/mol
Test Standard Observed
Assay (Purity) 99.5% min 99.7%
Density 3.119 g/mL 3.120 g/mL
Melting Point -7.2 °C -7.1 °C
Boiling Point 58.8 °C 58.9 °C
Moisture Content Not more than 0.1% 0.05%
Residue on Ignition Not more than 0.01% 0.005%
Related Substances None detected None detected

The above product is expected to comply with AR grade grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
AR grade 99.5% m.p. -7.2 °C; b.p. 58.8 °C Not more than 0.1% Not more than 0.01% None detected Solubility in water (25 °C): 0.2141 molL with formation of 0.00115 molL of HOBr
View full Technical Data Sheet

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